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Fundamentals of Optics
- Publisher
- Springer Journals
- Copyright
- Copyright © 2018 by Springer Science+Business Media, LLC, part of Springer Nature
- Subject
- Materials Science; Materials Science, general; Characterization and Evaluation of Materials; Polymer Sciences; Continuum Mechanics and Mechanics of Materials; Crystallography and Scattering Methods; Classical Mechanics
- ISSN
- 0022-2461
- eISSN
- 1573-4803
- DOI
- 10.1007/s10853-018-2489-8
- Publisher site
- See Article on Publisher Site
Abstract
The refractive index, polarizability and thermodynamic response of polystyrene under shock compression were investigated through experiments and theoretical analysis, and a relationship between the refractive index and the density, pressure and temperature of the polystyrene was obtained. Above a pressure of 20 GPa, an obvious inflexion was observed in how the refractive index of the polystyrene varied with the thermodynamic variables; in particular, it was found to depend strongly on the temperature (as obtained using a semiempirical complete equation of state). Relating the measured refractive index to the polarizability indicates that the polarizability decreased from 1.28 × 10−23 cm3 at ambient conditions, to 0.98 × 10−23 cm3 at pressure of 33 GPa, indicating that the lowest direct band gap $$ E_{t} $$ E t of polystyrene becomes < 2 eV, similar to that of many semiconductor materials.
Journal
Journal of Materials Science – Springer Journals
Published: May 29, 2018