Redox reaction Yb(III) + e = Yb(II) in a molten eutectic mixture NaCl-2CsCl

Redox reaction Yb(III) + e = Yb(II) in a molten eutectic mixture NaCl-2CsCl Potentiometric method was used to measure the redox potentials of Yb3+/Yb2+ in a eutectic melt of sodium and cesium chlorides relative to a chlorine reference electrode in the temperature range 823–973 K. The basic thermodynamic characteristics of the redox reaction YbCl2(s.) + 1/2Cl2(g.) ai YbCl3(s.) were calculated from the conditional standard potentials E*(Yb3+/Yb2+). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Redox reaction Yb(III) + e = Yb(II) in a molten eutectic mixture NaCl-2CsCl

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2009 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S107042720912009X
Publisher site
See Article on Publisher Site

Abstract

Potentiometric method was used to measure the redox potentials of Yb3+/Yb2+ in a eutectic melt of sodium and cesium chlorides relative to a chlorine reference electrode in the temperature range 823–973 K. The basic thermodynamic characteristics of the redox reaction YbCl2(s.) + 1/2Cl2(g.) ai YbCl3(s.) were calculated from the conditional standard potentials E*(Yb3+/Yb2+).

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Feb 1, 2010

References

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