The method of direct potentiometry was applied to measure redox potentials of Sm3 +/Sm2 + and Eu3 +/Eu2 + in molten cesium chloride relative to chlorine reference electrode in the temperature range 973-1173 K. Changes in the Gibbs energy of the redox reaction LnCl2(l) + 1/2Cl2(g) ↔ LnCl3(l) were calculated.
Russian Journal of Applied Chemistry – Springer Journals
Published: Oct 13, 2004
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