Reactions of the OH adducts of cytosine and its derivatives with TEMPO and TEMPOL: A steady state γ-radiolysis and pulse radiolysis study

Reactions of the OH adducts of cytosine and its derivatives with TEMPO and TEMPOL: A steady state... The reactions of the OH adducts of cytosine and its derivatives with nitroxides namely TEMPO and TEMPOL have been followed by steady state γ-radiolysis and pulse radiolysis. Pulse radiolysis studies show that the transient OH adducts of cytosine and its derivatives react with TEMPO and TEMPOL by electron transfer reaction and not by adduct formation as was observed in the case of thymine. The second order rate constants for these electron transfer reactions are of the order of 107 - 108 dm3 mol-1 s-1. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Reactions of the OH adducts of cytosine and its derivatives with TEMPO and TEMPOL: A steady state γ-radiolysis and pulse radiolysis study

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Publisher
Brill Academic Publishers
Copyright
Copyright © 2001 by VSP 2001
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856701317051680
Publisher site
See Article on Publisher Site

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