Reaction of products of thermal and thermal oxidative degradation of polyvinyl chloride with barium hydroxide

Reaction of products of thermal and thermal oxidative degradation of polyvinyl chloride with... The reaction of products of thermal and thermal oxidative degradation of polyvinyl chloride with barium hydroxide was studied. The degree of binding of chlorine and carbon atoms from polyvinyl chloride in reactions of barium hydroxide with hydrogen chloride and carbon dioxide formed by degradation and oxidation of the polymer was studied in relation to the hydroxide/polymer weight ratio and temperature. The activation energies of the reaction and the specific rates of formation of barium chloride and carbonate were calculated. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Reaction of products of thermal and thermal oxidative degradation of polyvinyl chloride with barium hydroxide

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Publisher
Springer Journals
Copyright
Copyright © 2012 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427212040234
Publisher site
See Article on Publisher Site

Abstract

The reaction of products of thermal and thermal oxidative degradation of polyvinyl chloride with barium hydroxide was studied. The degree of binding of chlorine and carbon atoms from polyvinyl chloride in reactions of barium hydroxide with hydrogen chloride and carbon dioxide formed by degradation and oxidation of the polymer was studied in relation to the hydroxide/polymer weight ratio and temperature. The activation energies of the reaction and the specific rates of formation of barium chloride and carbonate were calculated.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: May 17, 2012

References

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