Rapid hydrothermal synthesis of Li3VO4 with different favored facets

Rapid hydrothermal synthesis of Li3VO4 with different favored facets Here, we demonstrate a new, rapid, and flexible hydrothermal method using the V2O5 and LiOH as the precursors to synthesize Li3VO4. The ratios of precursor of V2O5 and LiOH can be changed in a wide range to control different preferred facets and morphologies, and the reason has been discussed from the structure of Li3VO4. The electrical performance of the Li3VO4 has also been systematically investigated. The thus-synthesized Li3VO4 exhibits significantly improved rate capability and cycling life compared with commercial graphite, synthesized Li4Ti5O12, and previously reported results on Li3VO4. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Solid State Electrochemistry Springer Journals
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Publisher
Springer Berlin Heidelberg
Copyright
Copyright © 2016 by Springer-Verlag Berlin Heidelberg
Subject
Chemistry; Physical Chemistry; Electrochemistry; Energy Storage; Characterization and Evaluation of Materials; Analytical Chemistry; Condensed Matter Physics
ISSN
1432-8488
eISSN
1433-0768
D.O.I.
10.1007/s10008-016-3462-6
Publisher site
See Article on Publisher Site

Abstract

Here, we demonstrate a new, rapid, and flexible hydrothermal method using the V2O5 and LiOH as the precursors to synthesize Li3VO4. The ratios of precursor of V2O5 and LiOH can be changed in a wide range to control different preferred facets and morphologies, and the reason has been discussed from the structure of Li3VO4. The electrical performance of the Li3VO4 has also been systematically investigated. The thus-synthesized Li3VO4 exhibits significantly improved rate capability and cycling life compared with commercial graphite, synthesized Li4Ti5O12, and previously reported results on Li3VO4.

Journal

Journal of Solid State ElectrochemistrySpringer Journals

Published: Nov 21, 2016

References

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