Radical copolymerization of N-vinylpyrrolidone with methyl methacrylate and styrene in the presence of C-phenyl-N-tert-butylnitrone

Radical copolymerization of N-vinylpyrrolidone with methyl methacrylate and styrene in the... The effect of C-phenyl-N-tert-butylnitrone on the features of radical copolymerization of N-vinylpyrrolidone with methyl methacrylate and styrene was examined. Nitrone exerts virtually no effect on the relative activities of the comonomers. At the same time, C-phenyl-N-tert-butylnitrone as a potential source of nitroxyl radical makes it possible to prepare copolymers of N-vinylpyrrolidone with methyl methacrylate and styrene to high conversions without gel effect, to control the molecular-weight characteristics of the copolymers, and to prepare block copolymers. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Radical copolymerization of N-vinylpyrrolidone with methyl methacrylate and styrene in the presence of C-phenyl-N-tert-butylnitrone

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Publisher
Nauka/Interperiodica
Copyright
Copyright © 2007 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427207010259
Publisher site
See Article on Publisher Site

Abstract

The effect of C-phenyl-N-tert-butylnitrone on the features of radical copolymerization of N-vinylpyrrolidone with methyl methacrylate and styrene was examined. Nitrone exerts virtually no effect on the relative activities of the comonomers. At the same time, C-phenyl-N-tert-butylnitrone as a potential source of nitroxyl radical makes it possible to prepare copolymers of N-vinylpyrrolidone with methyl methacrylate and styrene to high conversions without gel effect, to control the molecular-weight characteristics of the copolymers, and to prepare block copolymers.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Mar 10, 2007

References

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