The effect of C-phenyl-N-tert-butylnitrone on the features of radical copolymerization of N-vinylpyrrolidone with methyl methacrylate and styrene was examined. Nitrone exerts virtually no effect on the relative activities of the comonomers. At the same time, C-phenyl-N-tert-butylnitrone as a potential source of nitroxyl radical makes it possible to prepare copolymers of N-vinylpyrrolidone with methyl methacrylate and styrene to high conversions without gel effect, to control the molecular-weight characteristics of the copolymers, and to prepare block copolymers.
Russian Journal of Applied Chemistry – Springer Journals
Published: Mar 10, 2007
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