Radiation-initiated synthesis of tetrafluoroethylene telomers in 1,2-dibromotetrafluoroethane at a constant pressure of the monomer in the reactor

Radiation-initiated synthesis of tetrafluoroethylene telomers in 1,2-dibromotetrafluoroethane at... The kinetics of radiation-initiated telomerization of tetrafluoroethylene in a 1,2-dibromotetrafluoroethane solution at a constant concentration (pressure) of the monomer in the reactor was studied. The properties, molecular structure, and morphology of the telomers were studied by IR spectroscopy, scanning electron microscopy, and elemental and thermal gravimetric analyses. The synthesized telomers show promise for the development of fluoropolymeric nanocomposites and protective hydrophobic and antifriction coatings. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Radiation-initiated synthesis of tetrafluoroethylene telomers in 1,2-dibromotetrafluoroethane at a constant pressure of the monomer in the reactor

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Publisher
Pleiades Publishing
Copyright
Copyright © 2014 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S10704272140400211
Publisher site
See Article on Publisher Site

Abstract

The kinetics of radiation-initiated telomerization of tetrafluoroethylene in a 1,2-dibromotetrafluoroethane solution at a constant concentration (pressure) of the monomer in the reactor was studied. The properties, molecular structure, and morphology of the telomers were studied by IR spectroscopy, scanning electron microscopy, and elemental and thermal gravimetric analyses. The synthesized telomers show promise for the development of fluoropolymeric nanocomposites and protective hydrophobic and antifriction coatings.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jul 6, 2014

References

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