Radiation chemical investigations on aqueous solutions of C60(OH)18

Radiation chemical investigations on aqueous solutions of C60(OH)18 The ultraviolet-visible absorption spectrum of C60(OH)18 in water showed an absorption band with λmax = 215 nm and other characteristic absorption bands of C60 are not observed. The singlet-singlet and triplet-triplet absorption bands are not observed in the 400–900 nm region. It has low reactivity with e aq − and formed an absorption band with λmax = 580 nm. The hydroxyl radicals react with a bimolecular rate constant of 2.4×109 dm3 mol−1 s−1 and showed an absorption band at 540 nm. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Radiation chemical investigations on aqueous solutions of C60(OH)18

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Publisher
Springer Netherlands
Copyright
Copyright © 1997 by Springer
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856797X00150
Publisher site
See Article on Publisher Site

Abstract

The ultraviolet-visible absorption spectrum of C60(OH)18 in water showed an absorption band with λmax = 215 nm and other characteristic absorption bands of C60 are not observed. The singlet-singlet and triplet-triplet absorption bands are not observed in the 400–900 nm region. It has low reactivity with e aq − and formed an absorption band with λmax = 580 nm. The hydroxyl radicals react with a bimolecular rate constant of 2.4×109 dm3 mol−1 s−1 and showed an absorption band at 540 nm.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Apr 14, 2009

References

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