Pulse radiolysis study of 2-Mercapto-benzothiazole-a corrosion inhibitor

Pulse radiolysis study of 2-Mercapto-benzothiazole-a corrosion inhibitor Pulse radiolysis of 2-Mercaptobenzothiazole (2-MBT) has been undertaken in aqueous solution. The semi-oxidized species formed at pH 4.5 due to the reaction of OH•, Br2 •− and N3 • and at pH 10.5 with OH• yielded a spectrum with λmax = 348 and 595 nm. These semi-oxidized species were able to oxidize phenothiazine drugs (Eo⋟0.8 V). Reducing species such as eaq −, CO2 •− and H• atoms react with 2-MBT resulting in the formation of a transient having λmax = 350 nm and reducing in nature. Kinetic and spectroscopic data of interest are reported. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Pulse radiolysis study of 2-Mercapto-benzothiazole-a corrosion inhibitor

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Springer Netherlands
Copyright © 1997 by Springer
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
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