Pulse radiolysis studies of p-terphenyl in the ionic liquid methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide, [MeBu3N][NTf2]

Pulse radiolysis studies of p-terphenyl in the ionic liquid methyltributylammonium... The properties of intermediates resulting from radiolysis of solutions of p-terphenyl (TP) in the ionic liquid (IL) methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide ([MeBu3N][NTf2]) have been examined by pulse radiolysis. Pulse radiolysis of a solution of TP in [MeBu3N][NTf2] gives insight into the nature of the primary products of [MeBu3N][NTf2] radiolysis. The p-terphenyl anion radical (TP·−) is formed during radiolysis via a direct reaction with solvated electrons and reaction of singlet excited states (1TP*) with the electron donor triethylamine (Et3N). The TP* in the irradiated IL solution is formed by energy transfer from excited products of the IL itself and partly by direct photoexcitation of TP by Cherenkov light. To distinguish between the intermediates derived from the TP and to characterize the primary radiolysis products of [MeBu3N][NTf2], pulse radiolysis of the solutions was conducted under argon in the presence or absence of TP and/or Et3N. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Pulse radiolysis studies of p-terphenyl in the ionic liquid methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide, [MeBu3N][NTf2]

Loading next page...
 
/lp/springer_journal/pulse-radiolysis-studies-of-p-terphenyl-in-the-ionic-liquid-Ythl0P1gS1
Publisher
Springer Netherlands
Copyright
Copyright © 2014 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-014-1590-0
Publisher site
See Article on Publisher Site

Abstract

The properties of intermediates resulting from radiolysis of solutions of p-terphenyl (TP) in the ionic liquid (IL) methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide ([MeBu3N][NTf2]) have been examined by pulse radiolysis. Pulse radiolysis of a solution of TP in [MeBu3N][NTf2] gives insight into the nature of the primary products of [MeBu3N][NTf2] radiolysis. The p-terphenyl anion radical (TP·−) is formed during radiolysis via a direct reaction with solvated electrons and reaction of singlet excited states (1TP*) with the electron donor triethylamine (Et3N). The TP* in the irradiated IL solution is formed by energy transfer from excited products of the IL itself and partly by direct photoexcitation of TP by Cherenkov light. To distinguish between the intermediates derived from the TP and to characterize the primary radiolysis products of [MeBu3N][NTf2], pulse radiolysis of the solutions was conducted under argon in the presence or absence of TP and/or Et3N.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Apr 4, 2014

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve Freelancer

DeepDyve Pro

Price
FREE
$49/month

$360/year
Save searches from Google Scholar, PubMed
Create lists to organize your research
Export lists, citations
Access to DeepDyve database
Abstract access only
Unlimited access to over
18 million full-text articles
Print
20 pages/month
PDF Discount
20% off