Prospects of the use of aluminosilicate refractories for aluminum electrolyzers. Part 3. The role of the glass phase formed in the operation of aluminum electrolyzers

Prospects of the use of aluminosilicate refractories for aluminum electrolyzers. Part 3. The role... The compositions of glasses formed in the process of operation of an aluminum electrolyzer, the lowest content of aluminum at which the glass is separated into aluminosilicate and oxyfluoride components, and the temperatures of softening and of formation of drops of titanium-bearing glasses composition close to the glass in ShPD-45 refractory (with an additive of mullite-corundum chamotte) are determined. It is shown that the oxyfluoride glasses consist of both a silica skeleton and a corundum skeleton. The titanium-bearing glass phase can hinder penetration of aggressive gaseous byproducts of electrolysis. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Refractories and Industrial Ceramics Springer Journals

Prospects of the use of aluminosilicate refractories for aluminum electrolyzers. Part 3. The role of the glass phase formed in the operation of aluminum electrolyzers

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Publisher
Springer Journals
Copyright
Copyright © 2007 by Springer Science+Business Media, Inc.
Subject
Materials Science; Characterization and Evaluation of Materials; Materials Science, general; Ceramics, Glass, Composites, Natural Materials
ISSN
1083-4877
eISSN
1573-9139
D.O.I.
10.1007/s11148-008-9003-9
Publisher site
See Article on Publisher Site

Abstract

The compositions of glasses formed in the process of operation of an aluminum electrolyzer, the lowest content of aluminum at which the glass is separated into aluminosilicate and oxyfluoride components, and the temperatures of softening and of formation of drops of titanium-bearing glasses composition close to the glass in ShPD-45 refractory (with an additive of mullite-corundum chamotte) are determined. It is shown that the oxyfluoride glasses consist of both a silica skeleton and a corundum skeleton. The titanium-bearing glass phase can hinder penetration of aggressive gaseous byproducts of electrolysis.

Journal

Refractories and Industrial CeramicsSpringer Journals

Published: Jul 3, 2008

References

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