The influence of the chemical modification on the properties of syndiotactic 1,2-polybutadiene derivatives that contain various functional groups in macromolecules and show promise for practical use was studied. The dependence of the glass transition point and the fluidity and rheological properties of modified polydiene melts on the nature of the functional group in the macrochain and on the degree of the polymer functionalization was revealed. The possibility of directional synthesis of modified polymer products with the required operation characteristics on the basis of syndiotactic 1,2-polybutadiene was demonstrated.
Russian Journal of Applied Chemistry – Springer Journals
Published: Feb 9, 2017
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