A composition of the products of interaction in the system (NaPO3)3-Fe under heating was studied by X-ray analysis and calculation of ΔG T ○ . Possible pathways of the formation of iron phosphides of different chemical composition and other co-products during heating of sodium and iron cyclotriphophate to 1000°C were described on the basis of thermodynamic and X-ray data. The conditions for obtaining individual types of iron phosphides Fe3P, Fe2P, and FeP by interaction of sodium cyclotriphophate with metallic iron under heating were found.
Russian Journal of Applied Chemistry – Springer Journals
Published: Sep 13, 2014
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