Probable mechanism for alkane oxidation with H2O2 over VS-2

Probable mechanism for alkane oxidation with H2O2 over VS-2 Metallosilicate zeolites containing Ti and V, TS-2 and VS-2, have been synthesized using tetrabutylammonium cation as the template. Although both Ti and V exist in zeolite framework in a highly dispersed state, V easily leaches by K2CO3 or H2O2 treatments in contrast to Ti. Spin trapping experiments and relative reactivity of linear/cyclic alkanes indicate that the oxidation of alkanes over TS-2 and VS-2 proceed by different mechanisms; it is conceivable that the oxidation occurs by way of the attack of ·OH species produced from the V species in the zeolite framework with H2O2. Research on Chemical Intermediates Springer Journals

Probable mechanism for alkane oxidation with H2O2 over VS-2

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Springer Netherlands
Copyright © 1998 by Springer
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
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