Primary electron localization in polar liquids: Dependence on matrix and temperature

Primary electron localization in polar liquids: Dependence on matrix and temperature Computer generated structures of several polar liquids (water at 298 and 373 K, 1-propanol and 2-propanol at 298 K) have been analyzed in order to identify the regions of attractive potential that can serve as pre-existing sites for primary localization of an excess electron. Properties of pre-existing electron traps have been described in terms of statistical distributions of their geometrical parameters, energy levels and persistence times. The obtained results can explain, at least qualitatively, differences in the localization process in the considered matrices. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Primary electron localization in polar liquids: Dependence on matrix and temperature

Loading next page...
 
/lp/springer_journal/primary-electron-localization-in-polar-liquids-dependence-on-matrix-pyuN1uUN17
Publisher
Brill Academic Publishers
Copyright
Copyright © 2001 by VSP 2001
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/15685670152622086
Publisher site
See Article on Publisher Site

Abstract

Computer generated structures of several polar liquids (water at 298 and 373 K, 1-propanol and 2-propanol at 298 K) have been analyzed in order to identify the regions of attractive potential that can serve as pre-existing sites for primary localization of an excess electron. Properties of pre-existing electron traps have been described in terms of statistical distributions of their geometrical parameters, energy levels and persistence times. The obtained results can explain, at least qualitatively, differences in the localization process in the considered matrices.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Oct 7, 2004

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve Freelancer

DeepDyve Pro

Price
FREE
$49/month

$360/year
Save searches from Google Scholar, PubMed
Create lists to organize your research
Export lists, citations
Read DeepDyve articles
Abstract access only
Unlimited access to over
18 million full-text articles
Print
20 pages/month
PDF Discount
20% off