Preparation of Al, Cr, Nb, Mo, and W Monophosphides from a Lithium Metaphosphate Melt

Preparation of Al, Cr, Nb, Mo, and W Monophosphides from a Lithium Metaphosphate Melt Synthesis of a series of phosphides (AlP, CrP, NbP, MoP, and WP) by reactions of powdered metals with a melt of lithium metaphosphate LiPO3 was studied. Thermodynamic parameters (ΔH 0 2 9 8, ΔS 0 2 9 8, ΔG 0 2 9 8, and ΔG 0 1 2 7 3) of the reactions were calculated and their temperature modes were optimized on the basis of the standard thermodynamic characteristics of the initial substances and the reaction products. X-ray patterns of the powders of the obtained compounds are presented. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Preparation of Al, Cr, Nb, Mo, and W Monophosphides from a Lithium Metaphosphate Melt

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Publisher
Kluwer Academic Publishers-Plenum Publishers
Copyright
Copyright © 2001 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1023/A:1013741926277
Publisher site
See Article on Publisher Site

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