Preparation, chemical modification and absorption properties of various phthalocyanines

Preparation, chemical modification and absorption properties of various phthalocyanines A series of phthalocyanines were prepared from phthalodinitrile and corresponding metal salts by means of the ‘solvent’ methods. Some experiments were also conducted in the absence of a solvent in a ‘solvent-free’ process from phthalanhydride, urea and metal chlorides. All of the prepared phthalocyanines were modified by the incorporation of desirable functional groups in order to transform the virtually insoluble phthalocyanine skeleton into more soluble forms. Derivatives soluble in polar media were prepared by means of sulphonation, while those soluble in non-polar media were produced by chlorosulphonation with the subsequent condensation of prepared sulphochlorides with primary alkyl amines. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Preparation, chemical modification and absorption properties of various phthalocyanines

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Publisher
Springer Journals
Copyright
Copyright © 2009 by Springer Science+Business Media B.V.
Subject
Chemistry; Inorganic Chemistry ; Physical Chemistry ; Catalysis
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-008-0003-7
Publisher site
See Article on Publisher Site

Abstract

A series of phthalocyanines were prepared from phthalodinitrile and corresponding metal salts by means of the ‘solvent’ methods. Some experiments were also conducted in the absence of a solvent in a ‘solvent-free’ process from phthalanhydride, urea and metal chlorides. All of the prepared phthalocyanines were modified by the incorporation of desirable functional groups in order to transform the virtually insoluble phthalocyanine skeleton into more soluble forms. Derivatives soluble in polar media were prepared by means of sulphonation, while those soluble in non-polar media were produced by chlorosulphonation with the subsequent condensation of prepared sulphochlorides with primary alkyl amines.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Jan 13, 2009

References

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