Preparation, characterization and use of sulfonylbis(1,4-phenylene)bis(sulfamic acid) as an eco-benign, efficient, reusable and heterogeneous catalyst for the synthesis of mono- and bis-chromenes

Preparation, characterization and use of sulfonylbis(1,4-phenylene)bis(sulfamic acid) as an... Sulfonylbis(1,4-phenylene)bis(sulfamic acid) (SPSA) is easily prepared and recognized as a new heterogeneous catalyst by the reaction of 4,4′-sulfonyldianiline with chlorosulfonic acid. This reagent was used for the synthesis of the mono- and bis-chromene derivatives. All reactions were performed under mild reaction conditions in high to excellent yields. The advantages of using the SPSA as a heterogeneous catalyst in these reactions are: being environmentally friendly, low cost, commercially availability and easy to separate from the mixture of the reaction and high reusable catalyst. Using this catalyst, results in acceptable reaction time and high yields with high purity of the obtained products without utilizing any organic solvents. The catalyst was characterized by FT-IR, 1H NMR, 13C NMR, mass and TGA studies. All the products were characterized by FT-IR, 1H, 13C NMR, HRMS, melting point and elemental analyses. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of the Iranian Chemical Society Springer Journals

Preparation, characterization and use of sulfonylbis(1,4-phenylene)bis(sulfamic acid) as an eco-benign, efficient, reusable and heterogeneous catalyst for the synthesis of mono- and bis-chromenes

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Publisher
Springer Berlin Heidelberg
Copyright
Copyright © 2017 by Iranian Chemical Society
Subject
Chemistry; Analytical Chemistry; Inorganic Chemistry; Physical Chemistry; Biochemistry, general; Organic Chemistry
ISSN
1735-207X
eISSN
1735-2428
D.O.I.
10.1007/s13738-017-1128-7
Publisher site
See Article on Publisher Site

Abstract

Sulfonylbis(1,4-phenylene)bis(sulfamic acid) (SPSA) is easily prepared and recognized as a new heterogeneous catalyst by the reaction of 4,4′-sulfonyldianiline with chlorosulfonic acid. This reagent was used for the synthesis of the mono- and bis-chromene derivatives. All reactions were performed under mild reaction conditions in high to excellent yields. The advantages of using the SPSA as a heterogeneous catalyst in these reactions are: being environmentally friendly, low cost, commercially availability and easy to separate from the mixture of the reaction and high reusable catalyst. Using this catalyst, results in acceptable reaction time and high yields with high purity of the obtained products without utilizing any organic solvents. The catalyst was characterized by FT-IR, 1H NMR, 13C NMR, mass and TGA studies. All the products were characterized by FT-IR, 1H, 13C NMR, HRMS, melting point and elemental analyses.

Journal

Journal of the Iranian Chemical SocietySpringer Journals

Published: May 3, 2017

References

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