Preparation, characterization and catalytic activity of Bi−Mo-based catalysts for the oxidative dehydrogenation ofn-butene to 1,3-butadiene

Preparation, characterization and catalytic activity of Bi−Mo-based catalysts for the oxidative... Multicomponent bismuth molybdates were prepared by a co-precipitation method for use in the oxidative dehydrogenation ofn-butene to 1,3-butadiene. The effect of divalent and trivalent metals on the catalytic performance of multicomponent bismuth molybdate catalysts was investigated. It was found that the metal ratio of Fe/Bi/Mo=3∶1∶12 was favorable for the reaction. The successful formation of Ni X Co8−X Fe3Bi1Mo12O50 (X=0−8) catalysts was well confirmed by XRD and ICP-AES measurements. The multicomponent bismuth molybdate catalysts showed a better catalytic performance than the pure γ-Bi2MoO6 catalyst. Among the Ni X Co8−X Fe3Bi1Mo12O50 (X=0−8) catalysts, Ni3Co5Fe3Bi1Mo12O50 showed the highest yield of 1,3-butadiene. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Preparation, characterization and catalytic activity of Bi−Mo-based catalysts for the oxidative dehydrogenation ofn-butene to 1,3-butadiene

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Publisher
Springer Netherlands
Copyright
Copyright © 2008 by Springer
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/BF03036944
Publisher site
See Article on Publisher Site

Abstract

Multicomponent bismuth molybdates were prepared by a co-precipitation method for use in the oxidative dehydrogenation ofn-butene to 1,3-butadiene. The effect of divalent and trivalent metals on the catalytic performance of multicomponent bismuth molybdate catalysts was investigated. It was found that the metal ratio of Fe/Bi/Mo=3∶1∶12 was favorable for the reaction. The successful formation of Ni X Co8−X Fe3Bi1Mo12O50 (X=0−8) catalysts was well confirmed by XRD and ICP-AES measurements. The multicomponent bismuth molybdate catalysts showed a better catalytic performance than the pure γ-Bi2MoO6 catalyst. Among the Ni X Co8−X Fe3Bi1Mo12O50 (X=0−8) catalysts, Ni3Co5Fe3Bi1Mo12O50 showed the highest yield of 1,3-butadiene.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Apr 15, 2009

References

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