The results of mathematical simulation of the macrokinetics of butyl rubber synthesis (catalyst is aluminum chloride, solvent is methyl chloride, the synthesis temperature is T ≥ 173 K) in mixing and plug flow reactors were reported. A solution of inverse kinetic problem on identifying unknown rate constants of elementary reactions of a kinetic scheme was derived. A relation of speed of an agitator in the mixing reactor, concentration of a catalyst injected into the mixing reactor, a diameter of the plug flow reactor and velocity of the reaction mixture movement therein with the molecular weight characteristics of butyl rubber, its Mooney viscosity and strength properties of vulcanizates based on it were found.
Russian Journal of Applied Chemistry – Springer Journals
Published: Aug 15, 2015
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