Prediction of results of butyl rubber synthesis in mixing or plug flow reactors: an effect of factors controlling process on Mooney viscosity of butyl rubber and strength properties of its vulcanizates

Prediction of results of butyl rubber synthesis in mixing or plug flow reactors: an effect of... The results of mathematical simulation of the macrokinetics of butyl rubber synthesis (catalyst is aluminum chloride, solvent is methyl chloride, the synthesis temperature is T ≥ 173 K) in mixing and plug flow reactors were reported. A solution of inverse kinetic problem on identifying unknown rate constants of elementary reactions of a kinetic scheme was derived. A relation of speed of an agitator in the mixing reactor, concentration of a catalyst injected into the mixing reactor, a diameter of the plug flow reactor and velocity of the reaction mixture movement therein with the molecular weight characteristics of butyl rubber, its Mooney viscosity and strength properties of vulcanizates based on it were found. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Prediction of results of butyl rubber synthesis in mixing or plug flow reactors: an effect of factors controlling process on Mooney viscosity of butyl rubber and strength properties of its vulcanizates

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427215050146
Publisher site
See Article on Publisher Site

Abstract

The results of mathematical simulation of the macrokinetics of butyl rubber synthesis (catalyst is aluminum chloride, solvent is methyl chloride, the synthesis temperature is T ≥ 173 K) in mixing and plug flow reactors were reported. A solution of inverse kinetic problem on identifying unknown rate constants of elementary reactions of a kinetic scheme was derived. A relation of speed of an agitator in the mixing reactor, concentration of a catalyst injected into the mixing reactor, a diameter of the plug flow reactor and velocity of the reaction mixture movement therein with the molecular weight characteristics of butyl rubber, its Mooney viscosity and strength properties of vulcanizates based on it were found.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Aug 15, 2015

References

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