Predicting the Phase Stability of Sc1–x Ln x PO4 (Ln = Gd–Lu, Y) Zircon-Structured Solid Solutions

Predicting the Phase Stability of Sc1–x Ln x PO4 (Ln = Gd–Lu, Y) Zircon-Structured Solid... The energies of mixing (interaction parameters) in the Sc1–x Ln x PO4 (Ln = Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y) systems have been calculated using Urusov’s crystal energy theory of isomorphous substitutions. The decomposition (stability) temperatures of the solid solutions have been plotted against the atomic number of the rare-earth elements at x = 0.01, 0.03, 0.05, 0.10, 0.20, and 0.50. The present results can be helpful in a search for host and activator compositions for new luminescence, laser, and other materials based on the zircon-structured rare-earth orthophosphates. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Inorganic Materials Springer Journals

Predicting the Phase Stability of Sc1–x Ln x PO4 (Ln = Gd–Lu, Y) Zircon-Structured Solid Solutions

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Publisher
Springer Journals
Copyright
Copyright © 2018 by Pleiades Publishing, Ltd.
Subject
Chemistry; Inorganic Chemistry; Industrial Chemistry/Chemical Engineering; Materials Science, general
ISSN
0020-1685
eISSN
1608-3172
D.O.I.
10.1134/S0020168518060031
Publisher site
See Article on Publisher Site

Abstract

The energies of mixing (interaction parameters) in the Sc1–x Ln x PO4 (Ln = Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y) systems have been calculated using Urusov’s crystal energy theory of isomorphous substitutions. The decomposition (stability) temperatures of the solid solutions have been plotted against the atomic number of the rare-earth elements at x = 0.01, 0.03, 0.05, 0.10, 0.20, and 0.50. The present results can be helpful in a search for host and activator compositions for new luminescence, laser, and other materials based on the zircon-structured rare-earth orthophosphates.

Journal

Inorganic MaterialsSpringer Journals

Published: Jun 6, 2018

References

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