Practical neutral aromatic nitration with nitrogen dioxide in the presence of heterogeneous catalysts under moderate oxygen pressure

Practical neutral aromatic nitration with nitrogen dioxide in the presence of heterogeneous... A practical neutral aromatic nitration process using nitrogen dioxide in the presence of FeCl3 · 6H2O under 40–100 psig of oxygen was developed, and nitration of several aromatic compounds, including the deactivated nitrobenzene, was performed in a successful manner. The correlation of reaction rate with equivalents nitrogen dioxide, oxygen pressure, amount of catalyst and temperature was investigated through the nitration of benzene. Following the optimization of reaction conditions, the nitration of benzene was scaled up to 476 mol. Furthermore, inorganic solid catalysts with pore size over 5 Å and surface area over 100 m2/g were applied to newly developed neutral nitration. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Practical neutral aromatic nitration with nitrogen dioxide in the presence of heterogeneous catalysts under moderate oxygen pressure

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Publisher
Brill Academic Publishers
Copyright
Copyright © 2006 by VSP
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry; Catalysis
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856706778606534
Publisher site
See Article on Publisher Site

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