Polyvinyl alcohol-based nanocomposite hydrogels containing magnetic laponite RD to remove cadmium

Polyvinyl alcohol-based nanocomposite hydrogels containing magnetic laponite RD to remove cadmium In this study, magnetic nanocomposite hydrogels based on polyvinyl alcohol were synthesized. Magnetic polyvinyl alcohol/laponite RD (PVA-mLap) nanocomposites were characterized by scanning electron microscopy, X-ray diffraction, transmission electron microscopy, and Fourier transform infrared spectroscopy. The results indicated that PVA-mLap had desirable magnetic-sorption properties and magnetic-laponite nanoparticles were successfully synthesized and added to polyvinyl alcohol. The present nanocomposites were applied to remove Cd2+ from aqueous solution. The influence of initial Cd2+ concentration, magnetic-laponite concentration, pH, and ionic strength on adsorption isotherm was investigated. Heterogeneity of adsorption sites was intensified by increasing magnetic concentration of adsorbents and by rising pH value. Results of ionic strength studies indicated that by increasing ionic strength more than four times, the adsorption of Cd2+ has only decreased around 15%. According to the results, the dominant mechanism of Cd2+ sorption by the present adsorbents was determined chemical and specific sorption. Therefore, the use of the present nanocomposites as a powerful adsorbent of Cd2+ in the wastewater treatment is suggested. Isotherm data were described by using Freundlich and Langmuir models, and better fitting was introduced Langmuir model. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Environmental Science and Pollution Research Springer Journals

Polyvinyl alcohol-based nanocomposite hydrogels containing magnetic laponite RD to remove cadmium

Download PDF
12 pages
Read Article

Loading next page...
 
/lp/springer_journal/polyvinyl-alcohol-based-nanocomposite-hydrogels-containing-magnetic-txzL6mgiGG
Publisher
Springer Journals
Copyright
Copyright © 2018 by Springer-Verlag GmbH Germany, part of Springer Nature
Subject
Environment; Environment, general; Environmental Chemistry; Ecotoxicology; Environmental Health; Atmospheric Protection/Air Quality Control/Air Pollution; Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution
ISSN
0944-1344
eISSN
1614-7499
DOI
10.1007/s11356-018-1485-5
Publisher site
See Article on Publisher Site

Abstract

In this study, magnetic nanocomposite hydrogels based on polyvinyl alcohol were synthesized. Magnetic polyvinyl alcohol/laponite RD (PVA-mLap) nanocomposites were characterized by scanning electron microscopy, X-ray diffraction, transmission electron microscopy, and Fourier transform infrared spectroscopy. The results indicated that PVA-mLap had desirable magnetic-sorption properties and magnetic-laponite nanoparticles were successfully synthesized and added to polyvinyl alcohol. The present nanocomposites were applied to remove Cd2+ from aqueous solution. The influence of initial Cd2+ concentration, magnetic-laponite concentration, pH, and ionic strength on adsorption isotherm was investigated. Heterogeneity of adsorption sites was intensified by increasing magnetic concentration of adsorbents and by rising pH value. Results of ionic strength studies indicated that by increasing ionic strength more than four times, the adsorption of Cd2+ has only decreased around 15%. According to the results, the dominant mechanism of Cd2+ sorption by the present adsorbents was determined chemical and specific sorption. Therefore, the use of the present nanocomposites as a powerful adsorbent of Cd2+ in the wastewater treatment is suggested. Isotherm data were described by using Freundlich and Langmuir models, and better fitting was introduced Langmuir model.

Journal

Environmental Science and Pollution Research – Springer Journals

Published: Mar 17, 2018

References

  • Freeze-drying of nanoparticles: formulation, process and storage considerations
    Abdelwahed, W; Stainmesse, GDS; Fessi, H
  • Precipitation of Zn(II), Cu(II) and Pb(II) at bench-scale using biogenic hydrogen sulfide from the utilization of volatile fatty acids
    Alvarez, MT; Crespo, C; Mattiasson, B
  • Preparation of composites of laponite with alginate and alginic acid polysaccharides
    Bandeira, LC; Calefi, PS; Ciuffi, KJ; Faria, EH; Nassar, EJ; Vicente, MA; Trujillano, R
  • Cadmium removal from aqueous solutions by chitin: kinetic and equilibrium studies
    Benguella, B; Benaissa, H
  • Removal of cadmium from aqueous solution using low molecular weight chitosan derivative
    Boamah, PO; Huang, Y; Hua, M; Zhang, Q; Liua, Y; Onumah, J; Wang, W; Yongxiu Song, Y
  • Adsorption isotherms and breakthrough curves to study how humic acids influence heavy metal-soil interactions
    Calace, N; Deriu, D; Petronio, BM; Pietroletti, PM
  • Removal of copper from aqueous solution by chitosan in prawn shell: adsorption equilibrium and kinetics
    Chu, K
  • The iron oxides: structure, properties, reactions, occurrences and uses
    Cornell, RM; Schwertmann, U
  • Selective removal of the heavy metal ions from waters and industrial wastewaters by ion-exchange method
    Dabrowski, A; Hubicki, Z; Podkoscielny, P; Robens, E
  • Adsorption of cadmium and humic acid onto hematite
    Davis, AP; Bhatnagar, V
  • Poly (vinyl alcohol) (PVA)-enhanced hybrid hydrogels of hyperbranched poly (ether amine) (hPEA) for selective adsorption and separation of dyes
    Deng, SH; Xu, H; Jiang, X; Yin, J
  • Optimization of the electrocoagulation process for the removal of copper, lead and cadmium in natural waters and simulated wastewater
    Escobar, C; Soto-Salazar, C; Toral, I
  • Removal of heavy metal ions from wastewaters: a review
    Fu, F; Wang, Q
  • Polyacrylic acid-grafted magnetite nanoparticles for remediation of Pb(II)-contained water
    Guan, X; Yan, X; Zeng, S; Xu, Q; Chen, Z; Fan, H
  • Aggregation of cationic p-phenylene ethynylenes on Laponite clay in aqueous dispersions and solid films
    Hill, EH; Zhang, Y; Whitten, DG
  • Calcium hydroxyapatite microfibrillated cellulose composite as a potential adsorbent for the removal of Cr(VI) from aqueous solution
    Hokkanen, S; Bhatnagar, A; Repo, E; Lou, S; Sillanpää, M
  • Removal of heavy metals from industrial wastewaters by adsorption onto activated carbon prepared from an agricultural solid waste
    Kadirvelu, K; Thamaraiselvi, K; Namasivayam, C
  • Rapid and high capacity adsorption of heavy metals by Fe3O4/montmorillonite nanocomposite using response surface methodology: preparation, characterization, optimization, equilibrium isotherms, and adsorption kinetics study
    Kalantari, K; Ahmad, MB; Masoumi, HRF; Shameli, K; Basri, M; Khandanlou, R
  • Removal of Cd(II) ions from aqueous solution and industrial effluent using reverse osmosis and nanofiltration membranes
    Kheriji, J; Tabassi, D; Hamrouni, B
  • The effect of poly (vinyl alcohol) on cadmium adsorption and desorption from alginate adsorbents
    Klimiuk, E; Kuczajowska-Zadrozna, M
  • The removal of zinc from synthetic wastewaters by micellar-enhanced ultrafiltration: statistical design of experiments
    Landaburu-Aguirre, J; Garcıa, V; Pongracz, E; Keiski, RL
  • Synthesis and self-assembly of amphiphilic Janus laponite disks
    Liu, J; Liu, G; Zhang, M; Sun, P; Zhao, H
  • In situ synthesis of magnetic Cara PVA IPN nanocomposite hydrogels and controlled drug release
    Mahdavinia, GR; Etemadi, H
  • Magnetic/pH-responsive beads based on caboxymethyl chitosan and κ-carrageenan and controlled drug release
    Mahdavinia, GR; Etemadi, H; Soleymani, F
  • Synthesis and characterization of hydroxypropyl methylcellulose-g-poly (acrylamide)/LAPONITE® RD nanocomposites as novel magnetic- and pH-sensitive carriers for controlled drug release
    Mahdavinia, GR; Ettehadi, S; Amini, M; Sabzi, M
  • Magnetic-hydrogel beads based on PVA/sodium alginate/laponite RD and studying their BSA adsorption
    Mahdavinia, GR; Mousanezhad, S; Hosseinzadeh, H; Darvishi, F; Sabzi, M
  • Novel magnetic polyvinyl alcohol/laponite RD nanocomposite hydrogels for efficient removal of methylene blue
    Mahdavinia, GR; Soleymani, M; Sabzi, M; Azimi, HR; Atlasi, Z
  • On the kinetics of precipitate flotation of Cr III using sodium dodecylsulfate and ethanol
    Medina, BY; Torem, ML; Mesquita, LMS
  • The role of sorbed humic substances on the distribution of organic and inorganic contaminants in groundwater
    Murphy, EM; Zachara, JM
  • Physicochemical characterization and biocompatibility in vitro of biphasic calcium phosphate/polyvinyl alcohol scaffolds prepared by freeze-drying method for bone tissue engineering applications
    Nie, L; Chen, D; Suo, J; Zou, P; Feng, S; Yang, Q; Yang, S; Ye, S
  • Development of polymeric and polymer-based hybrid adsorbents for pollutants removal from waters
    Pan, B; Pan, B; Zhang, W; Lv, L; Zhang, Q; Zheng, S
  • Enhanced defluoridation and facile separation of magnetic nano-hydroxyapatite/alginate composite
    Pandi, K; Viswanathan, N
  • Magnetically separable reduced graphene oxide/iron oxide nanocomposite materials for environmental remediation
    Peik-See, T; Pandikumar, A; Ngee, LH; Ming, HN; Hua, CC
  • Mesoporous carbon derived from a biopolymer and a clay: preparation, characterization and application for an organochlorine pesticide adsorption
    Pinto, MDE; Goncalves, RGL; Santos, RMM; Araujo, EA; Perotti, GF; Macedo, RD; Bizeto, MA; Constantino, VRL; Pinto, FG; Tronto, J
  • X-ray diffraction analysis of poly(vinyl alcohol) hydrogels, obtained by freezing and thawing techniques
    Ricciardi, R; Auriemma, F; Rosa, C; Laupretre, F
  • Derivation of the fruendlich equation of ion exchange reactions in soils
    Sposito, G
  • Preparation and characterization of Fe3O4/CdTe magnetic/fluorescent nanocomposites and their applications in immuno-labeling and fluorescent imaging of cancer cells
    Sun, P; Zhang, H; Liu, C; Fang, J; Wang, M; Chen, J; Zhang, J; Mao, C; Xu, S
  • Cation binding by humic substances
    Tipping, E
  • Immobilization of magnetic iron oxide nanoparticles on laponite discs–an easy way to biocompatible ferrofluids and ferrogels
    Tzitzios, V; Basina, G; Bakandritsos, A; Hadjipanayis, CG; Mao, H; Niarchos, D; Hadjipanayis, GC; Tucek, J; Zboril, R
  • Physically crosslinked poly (vinyl alcohol) hydrogels with magnetic field controlled modulus
    Wu, J; Gong, X; Fan, Y; Xia, H
  • Preparation and characterization of magnetic rectorite/iron oxide nanocomposites and its application for the removal of the dyes
    Wu, D; Zheng, P; Chang, PR; Ma, X

You’re reading a free preview. Subscribe to read the entire article.

Try 2 weeks free now

DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

or browse the journals available

Search

Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly

Organize

Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.

Access

Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve

Freelancer

DeepDyve

Pro

Price

FREE

$49/month
$360/year

Save searches from
Google Scholar,
PubMed

Create folders to
organize your research

Export folders, citations

Read DeepDyve articles

Abstract access only

Unlimited access to over
18 million full-text articles

Print

20 pages / month

PDF Discount

20% off

Sign up
for free
Start 14 day
Free Trial