Polyhydroxyquinoline-carbon nanotube chelating resin for selective adsorption of lead ions: multivariate optimization, isothermic, and thermodynamic study

Polyhydroxyquinoline-carbon nanotube chelating resin for selective adsorption of lead ions:... In this work a facile hydrothermal route has been employed to prepare a multiwall carbon nanotube wrapped in a chelating resin. 8-Hydroxyquinoline and p-formaldehyde were used as monomer and linker for polymer synthesis. The prepared composite was employed as an efficient adsorbent for lead adsorption and preconcentration from various matrices. Effective parameters on lead adsorption have been optimized by central composite design. Results showed that equilibrium adsorption was obtained at pH = 4, with a shacking time of 15 min and adsorbent dosage of 15 mg. Isotherm study showed that the sorbent has adsorbent capacity of 250 mg g−1; moreover, the process followed a Langmuir isotherm model. Thermodynamic investigation confirmed that lead adsorption is spontaneous, as well as follows endothermic path. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Polyhydroxyquinoline-carbon nanotube chelating resin for selective adsorption of lead ions: multivariate optimization, isothermic, and thermodynamic study

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Publisher
Springer Netherlands
Copyright
Copyright © 2016 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-016-2650-4
Publisher site
See Article on Publisher Site

Abstract

In this work a facile hydrothermal route has been employed to prepare a multiwall carbon nanotube wrapped in a chelating resin. 8-Hydroxyquinoline and p-formaldehyde were used as monomer and linker for polymer synthesis. The prepared composite was employed as an efficient adsorbent for lead adsorption and preconcentration from various matrices. Effective parameters on lead adsorption have been optimized by central composite design. Results showed that equilibrium adsorption was obtained at pH = 4, with a shacking time of 15 min and adsorbent dosage of 15 mg. Isotherm study showed that the sorbent has adsorbent capacity of 250 mg g−1; moreover, the process followed a Langmuir isotherm model. Thermodynamic investigation confirmed that lead adsorption is spontaneous, as well as follows endothermic path.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Aug 18, 2016

References

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