Polyfluoroalkyl Chlorosulfites as New Polyfluorinating Agents

Polyfluoroalkyl Chlorosulfites as New Polyfluorinating Agents The interaction of polyfluorinated alcohols with triethylamine and the kinetics of the reaction of the resulting triethylamine complexes with thionyl chloride were studied, the mechanism of formation of polyfluoroalkyl chlorosulfites was considered, and the optimal reaction conditions were found. The alkylating power of polyfluoroalkyl chlorosulfites was studied in reactions with alkali metal halides (to obtain polyfluorohaloalkanes), in synthesis of acrylic and methacrylic acid esters, and in synthesis of polyfluoroalkyl ethers (with polyfluoroalkyl 1-adamantyl ethers as example). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Polyfluoroalkyl Chlorosulfites as New Polyfluorinating Agents

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Publisher
Springer Journals
Copyright
Copyright © 2002 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1023/A:1020788902312
Publisher site
See Article on Publisher Site

Abstract

The interaction of polyfluorinated alcohols with triethylamine and the kinetics of the reaction of the resulting triethylamine complexes with thionyl chloride were studied, the mechanism of formation of polyfluoroalkyl chlorosulfites was considered, and the optimal reaction conditions were found. The alkylating power of polyfluoroalkyl chlorosulfites was studied in reactions with alkali metal halides (to obtain polyfluorohaloalkanes), in synthesis of acrylic and methacrylic acid esters, and in synthesis of polyfluoroalkyl ethers (with polyfluoroalkyl 1-adamantyl ethers as example).

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Oct 13, 2004

References

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