Photoinduced electron transfer between adamantanamine-(OCH2CH2) n -phenothiazine and mono-6-p-nitrobenzoyl-β-cyclodextrin

Photoinduced electron transfer between adamantanamine-(OCH2CH2) n -phenothiazine and... A series of adamantanamine-(OCH2CH2) n -phenothiazine (n = 0, 1, 2, 3) electron donors was synthesized. Photoinduced electron transfer was observed in the supramolecular complex of the phenothiazine derivatives with p-nitrobenzoyl-β-cyclodextrin (NBCD) through binding of the adamantyl group by the NBCD cavity, which is stabilized clearly via hydrophobic interactions in aqueous solution. Detailed Stern–Volmer constants were measured and they were partitioned into dynamic Stern–Volmer quenching constants and static binding constants. The results revealed an efficient electron transfer process inside the supramolecular systems compared to that controlled by diffusion. This observation also indicates that the chain length will influence the electron transfer efficiency of a supramolecular donor–acceptor system. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Photoinduced electron transfer between adamantanamine-(OCH2CH2) n -phenothiazine and mono-6-p-nitrobenzoyl-β-cyclodextrin

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Publisher
Brill Academic Publishers
Copyright
Copyright © 2005 by VSP
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry; Catalysis
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856705774576245
Publisher site
See Article on Publisher Site

Abstract

A series of adamantanamine-(OCH2CH2) n -phenothiazine (n = 0, 1, 2, 3) electron donors was synthesized. Photoinduced electron transfer was observed in the supramolecular complex of the phenothiazine derivatives with p-nitrobenzoyl-β-cyclodextrin (NBCD) through binding of the adamantyl group by the NBCD cavity, which is stabilized clearly via hydrophobic interactions in aqueous solution. Detailed Stern–Volmer constants were measured and they were partitioned into dynamic Stern–Volmer quenching constants and static binding constants. The results revealed an efficient electron transfer process inside the supramolecular systems compared to that controlled by diffusion. This observation also indicates that the chain length will influence the electron transfer efficiency of a supramolecular donor–acceptor system.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Nov 1, 2005

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