Photoelectric properties of Cz-Py-MV2+ monolayer films

Photoelectric properties of Cz-Py-MV2+ monolayer films Diaza-18-crown-6-ethers appending two pyrenyl (Py-C) or two carbazolyl (Cz-C) groups form 1 : 1 host–guest complexes with methyl viologen chloride (MV2+). These complexes were assembled into monolayers by Langmuir-Blodgett (L-B) technique. The generated assembly involves the general structure of donor-sensitizer-acceptor (Cz-Py-MV2+) in space, although any of the photo- and redox-active components are not covalently bonded. This assembly was transferred on an indiumtin oxide (ITO) glass to fabricate an electrode. The photoinduced voltage of this electrode was measured with a saturated calomel reference electrode in hydroquinone (H2Q) solution to be ca. 168 mV with the light intensity of ca. 218 mW/cm2. This electrode was used as the light electrode to construct a photogalvanic cell with a platinum electrode as the dark electrode. Irradiation of the light electrode resulted in anodic photocurrent. The effects of light intensity, bias voltage, concentration of H2Q and oxygen on the photocurrent were investigated. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Photoelectric properties of Cz-Py-MV2+ monolayer films

Loading next page...
 
/lp/springer_journal/photoelectric-properties-of-cz-py-mv2-monolayer-films-rIp5QuCPFo
Publisher
Brill Academic Publishers
Copyright
Copyright © 2002 by VSP 2002
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry; Catalysis
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/15685670260373281
Publisher site
See Article on Publisher Site

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

Monthly Plan

  • Read unlimited articles
  • Personalized recommendations
  • No expiration
  • Print 20 pages per month
  • 20% off on PDF purchases
  • Organize your research
  • Get updates on your journals and topic searches

$49/month

Start Free Trial

14-day Free Trial

Best Deal — 39% off

Annual Plan

  • All the features of the Professional Plan, but for 39% off!
  • Billed annually
  • No expiration
  • For the normal price of 10 articles elsewhere, you get one full year of unlimited access to articles.

$588

$360/year

billed annually
Start Free Trial

14-day Free Trial