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Photocycloaddition reaction of methyl 2- and 3-chromonecarboxylates with various alkenes

Photocycloaddition reaction of methyl 2- and 3-chromonecarboxylates with various alkenes The irradiation of methyl 2- and 3-chromonecarboxylate in the presence of various alkenes afforded cyclobutane type adducts, whose structures were established by X-ray structural analysis. Methyl 2-chromonecarboxylate showed higher photochemical reactivity than methyl 3-chromonecarboxylate, in which endo adducts were yielded as major products. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Photocycloaddition reaction of methyl 2- and 3-chromonecarboxylates with various alkenes

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References (17)

Publisher
Springer Journals
Copyright
Copyright © 2012 by Springer Science+Business Media B.V.
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
DOI
10.1007/s11164-012-0656-0
Publisher site
See Article on Publisher Site

Abstract

The irradiation of methyl 2- and 3-chromonecarboxylate in the presence of various alkenes afforded cyclobutane type adducts, whose structures were established by X-ray structural analysis. Methyl 2-chromonecarboxylate showed higher photochemical reactivity than methyl 3-chromonecarboxylate, in which endo adducts were yielded as major products.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Jun 20, 2012

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