Photochemical reaction intermediates of benzyl chloride in condensed phase

Photochemical reaction intermediates of benzyl chloride in condensed phase Reaction intermediates produced upon the photolysis of benzyl chloride have been studied in glassy matrix and in solution. In the steady-state photolysis both benzyl radicals and structural isomers of benzyl chloride were formed in ethanol, while in 3-methylpentane the structural isomers were predominantly formed. The nanosecond laser photolyses of benzyl chloride in ethanol and in cyclohexane also generated benzyl radicals and structural isomers at room temperature. In acetonitrile, in addition to these species, benzyl cations were observed in the early stage after the photolysis. Research on Chemical Intermediates Springer Journals

Photochemical reaction intermediates of benzyl chloride in condensed phase

Loading next page...
Brill Academic Publishers
Copyright © 2001 by VSP 2001
Chemistry; Inorganic Chemistry; Physical Chemistry
Publisher site
See Article on Publisher Site


You’re reading a free preview. Subscribe to read the entire article.

DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

Monthly Plan

  • Read unlimited articles
  • Personalized recommendations
  • No expiration
  • Print 20 pages per month
  • 20% off on PDF purchases
  • Organize your research
  • Get updates on your journals and topic searches


Start Free Trial

14-day Free Trial

Best Deal — 39% off

Annual Plan

  • All the features of the Professional Plan, but for 39% off!
  • Billed annually
  • No expiration
  • For the normal price of 10 articles elsewhere, you get one full year of unlimited access to articles.



billed annually
Start Free Trial

14-day Free Trial