Access the full text.
Sign up today, get DeepDyve free for 14 days.
Loading next page...
/lp/springer_journal/photocatalytic-mineralization-of-chlorinated-organic-pollutants-in-06fd0oXSMY
References (33)
-
A. Hiskia, E. Papaconstantinou (1992)
Photocatalytic oxidation of organic compounds by polyoxometalates of molybdenum and tungsten : catalyst regeneration by dioxygenInorganic Chemistry, 31
-
H. Einaga, M. Misono (1996)
Photocatalysis of H3PW12O40 for 4-Chlorophenol Decomposition in Aqueous MediaBulletin of the Chemical Society of Japan, 69
-
A. Hiskia, A. Mylonas, D. Tsipi, E. Papaconstantinou (1997)
Photocatalytic Degradation of Lindane in Aqueous SolutionPesticide Science, 50
-
R. Bailey, H. Clark, S. Krause, J. Ferris, R. Strong (1979)
Chemistry of the Environment -
P. Kamat (1993)
PHOTOCHEMISTRY ON NONREACTIVE AND REACTIVE (SEMICONDUCTOR) SURFACESChemical Reviews, 93
-
C. Minero, E. Pelizzetti, P. Pichat, M. Sega, M. Vincenti (1995)
Formation of Condensation Products in Advanced Oxidation Technologies: The Photocatalytic Degradation of Dichlorophenols on TiO2.Environmental science & technology, 29 9
-
A. Mylonas, E. Papaconstantinou (1996)
On the mechanism of photocatalytic degradation of chlorinated phenols to CO2 and HCl by polyoxometalatesJournal of Photochemistry and Photobiology A-chemistry, 94
-
D. Ollis, E. Pelizzetti, N. Serpone (1991)
Photocatalyzed destruction of water contaminantsEnvironmental Science & Technology, 25
-
E. Papaconstantinou, P. Argitis, D. Dimoticali, A. Hiskia, A. Ioannidis (1986)
Photocatalytic Oxidation of Organic Compounds with Heteropoly Electrolytes. Aspects on Photochemical Utilization of Solar Energy -
A. Mylonas, E. Papaconstantinou (1994)
Photocatalytic degradation of chlorophenols to CO2 and HCl with polyoxotungstates in aqueous solutionJournal of Molecular Catalysis, 92
-
R. Neumann, M. Levin (1992)
Aerobic oxidative dehydrogenations catalyzed by the mixed-addenda heteropolyanion PV2Mo10O405- : a kinetic and mechanistic studyJournal of the American Chemical Society, 114
-
H. Einaga, M. Misono (1997)
Photocatalyzed Decomposition of 4-Chlorophenol by Keggin-Type HeteropolytungstateBulletin of the Chemical Society of Japan, 70
-
T. Florence, Y. Farrar (1971)
Spectrophotometric determination of chloride at the parts-per-billion level by the mercury(II) thiocyanate methodAnalytica Chimica Acta, 54
-
M. Siddiqui, M.C. Saxena, A. Bhargava, T.D. Seth, C. Murti, D. Kutty (1981)
Agrochemicals in the maternal blood, milk, and cord blood: a source of toxicants for prenates and neonates.Environmental research, 24 1
-
M. Pope, A. Müller (1991)
Polyoxometalate Chemistry: An Old Field with New Dimensions in Several DisciplinesAngewandte Chemie, 30
-
R. Bailey, H. Clark, J. Ferris, S. Krause, R. Strong (1978)
7 – PESTICIDES, POLYCHLORINATED BIPHENYLS, AND OTHER CHLORO-ORGANIC COMPOUNDS -
C. Holden (1976)
Mirex: persistent pesticide on its way out.Science, 194 4262
-
M. Trillas, J. Peral, X. Doménech (1996)
Photocatalyzed Degradation of Phenol, 2,4‐Dichlorophenol, Phenoxyacetic Acid and 2,4‐Dichlorophenoxyacetic Acid over SupportedTiO2 in a Flow SystemJournal of Chemical Technology & Biotechnology, 67
-
E. Papaconstantinou (1989)
Photochemistry of polyoxometallates of molybdenum and tungsten and/or vanadiumChemical Society Reviews, 18
-
M. Hoffmann, S. Martin, W. Choi, D. Bahnemann (1995)
Environmental Applications of Semiconductor PhotocatalysisChemical Reviews, 95
-
A. Rossi, A. Tournebize, P. Boule (1995)
Phototransformation of chlorohydroquinone in aqueous solutionJournal of Photochemistry and Photobiology A-chemistry, 85
-
M. Pope, G. Varga (1966)
Heteropoly Blues. I. Reduction Stoichiometries and Reduction Potentials of Some 12-TungstatesInorganic Chemistry, 5
-
L. Keith, W. Telliard (1979)
PRIORITY POLLUTANTS I-A PERSPECTIVES VIEWEnvironmental Science & Technology, 13
-
V. Day, W. Klemperer (1985)
Metal Oxide Chemistry in Solution: The Early Transition Metal PolyoxoanionsScience, 228
-
A. Mylonas, E. Papaconstantinou, V. Roussis (1996)
Photocatalytic degradation of phenol and p-cresol by polyoxotungstates. mechanistic implicationsPolyhedron, 15
-
G. Varga, E. Papaconstantinou, M. Pope (1970)
Heteropoly blues. IV. Spectroscopic and magnetic properties of some reduced polytungstatesInorganic Chemistry, 9
-
D. Duncan, C. Hill (1997)
Mechanism of Reaction of Reduced Polyoxometalates with O2 Evaluated by 17O NMRJournal of the American Chemical Society, 119
-
O. Legrini, E. Oliveros, A. Braun (1993)
Photochemical processes for water treatmentChemical Reviews, 93
-
A. Mylonas, A. Hiskia, E. Papaconstantinou (1996)
Contribution to water purification using polyoxometalates. Aromatic derivatives, chloroacetic acidsJournal of Molecular Catalysis A-chemical, 114
-
Jean-Christophe D'Oliveira, C. Minero, E. Pelizzetti, P. Pichat (1993)
Photodegradation of dichlorophenols and trichlorophenols in TiO2 aqueous suspensions: kinetic effects of the positions of the Cl atoms and identification of the intermediatesJournal of Photochemistry and Photobiology A-chemistry, 72
-
J. Knuutinen, I. Korhonen (1983)
Mass spectra of chlorinated aromatics formed in pulp bleaching: I—chlorinated catecholsJournal of Mass Spectrometry, 18
-
R. Matthews (1988)
Kinetics of photocatalytic oxidation of organic solutes over titanium dioxideJournal of Catalysis, 111
-
H. Kay (1980)
Environmental Health CriteriaJournal of Clinical Pathology, 33
- Publisher
- Springer Journals
- Copyright
- Copyright © 2000 by VSP
- Subject
- Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
- ISSN
- 0922-6168
- eISSN
- 1568-5675
- DOI
- 10.1163/156856700X00750
- Publisher site
- See Article on Publisher Site
Abstract
Homogeneous aqueous solutions of organochlorine pesticides and chlorophenols, namely, lindane, hexachlorobenzene and 2,4-dichlorophenol (2,4DCP), undergo effective photodegradation upon photolysis with UV and near visible light in the presence of a characteristic polyoxometallate catalyst PW12O40 3−. These substrates remained, practically, intact (lindane, HCB) or underwent minor degradation under similar conditions in absence of catalyst. The main oxidant appears to be OH radicals formed by the reaction of the excited polyoxometallate with H2O. The system compares with the widely published TiO2. Chlorohydroquinone (ClHQ), hydroquinone (HQ), chlorobenzoquinone (ClBQ), benzoquinone (BQ), 3,5-dichlorocatechol (3,5DCC) and 4-chlorocatechol (4CC), among others, were identified as the main aromatic intermediates in the photodegradation of 2,4DCP. Acetic acid was detected as ring cleavage product. In all cases the final photodegradation leads to complete mineralization of substrates to CO2 and HCl.
Journal
Research on Chemical Intermediates – Springer Journals
Published: Jan 1, 2000