www.nature.com/scientificreports OPEN Photo-acoustic spectroscopy revealing resonant absorption of self-assembled GaAs-based Received: 18 January 2017 nanowires Accepted: 19 April 2017 Published: xx xx xxxx 1 1 1 1 1 Grigore Leahu , Emilija Petronijevic , Alessandro Belardini , Marco Centini , Roberto Li Voti , 2 2 2 1 Teemu Hakkarainen , Eero Koivusalo , Mircea Guina & Concita Sibilia III–V semiconductors nanowires (NW) have recently attracted a significant interest for their potential application in the development of high efficiency, highly-integrated photonic devices and in particular for the possibility to integrate direct bandgap materials with silicon-based devices. Here we report the absorbance properties of GaAs-AlGaAs-GaAs core-shell-supershell NWs using photo-acoustic spectroscopy (PAS) measurements in the spectral range from 300 nm to 1100 nm wavelengths. The NWs were fabricated by self-catalyzed growth on Si substrates and their dimensions (length ~5 μm, diameter ~140–150 nm) allow for the coupling of the incident light to the guided modes in near-infrared (IR) part of the spectrum. This coupling results in resonant absorption peaks in the visible and near IR clearly evidenced by PAS. The analysis reveal broadening of the resonant absorption peaks arising from the NW size distribution and the interaction with other NWs. The results show that the PAS technique, directly providing scattering independent absorption spectra, is a very useful tool for the characterization and investigation of vertical NWs as well as for the design of NW ensembles for photonic applications, such as Si-integrated light sources, solar cells, and wavelength dependent photodetectors. e Th growing need for fast, integrated, nanoscale, low-cost photonic devices has triggered intensive developments of semiconductor nanowires (NWs). Main efforts have been directed to realize high quality nano-structures that are able to confine optical fields, and enhance the electrical and optical response in nano-scale dimensions. A single III-V semiconductor vertical NW has good waveguiding properties for energies above the bandgap owing to high refractive indices, and it can support a number of discrete photonic modes. These confined modes can lead to resonant absorption at specific wavelengths mainly defined by the combination of materials properties and their geometric dimensions . The coupling of light to guided modes is essential for light harvesting and lasing applications; for example for the demonstration of NW lasing up to room temperature , and monolithic inte- gration of NW lasers on Si . The resonant absorption in NWs has been studied numerically: for single NWs and 4 5 NW arrays , and for both parallel and normal excitation with respect to the long NW axis . Recently, wavelength 6 7 selective photodetectors and spin angular momentum generation based on the absorption enhancement have been proposed. Recent developments in fabrication of semiconductor NWs have already lead to a vast range of 8–11 12, 13 14 15 16 applications: photo voltaics , light sources , waveguides , photodetectors and water reduction , all of which exploit the confining properties of the NWs. In particular, NW solar cells reaching efficiencies up to 15.3% have been recently demonstrated owing to resonant absorption enabling bulk-like photocurrent generation with greatly reduced material consumption . Furthermore, NWs can exhibit nonlinear optics effects as second har - monic generation and finally, the hybridization of dielectric NWs with metallic layers and/or nanostructures 19 20–22 oer ff s a wide range of new application possibilities such as novel yagi-uda antennas , and plasmonic lasers . Although the optical and electrical properties have been widely investigated and well understood, the char- acterization techniques are usually based on the indirect measurements of the resonant absorption by means 23 24 25–27 of transmission/reflection , photocurrents or photoluminescence excitation . Recently, a scattering free Dipartimento di Scienze di Base ed Applicate per l’Ingegneria, Sapienza Università di Roma, A. Scarpa 16, 00161, Rome, Italy. Optoelectronics Research Centre, Tampere University of Technology, Korkeakoulunkatu 3, 33720, Tampere, Finland. Correspondence and requests for materials should be addressed to E.P. (email: emilija. firstname.lastname@example.org) Scientific Repo R ts | 7: 2833 | DOI:10.1038/s41598-017-02839-1 1 www.nature.com/scientificreports/ Figure 1. (a) Vertical schematic of the NWs of the length L, where k is always parallel to L and normally incident on the cross section. (b) Cross section of the NWs with overall diameter D, which comprises GaAs core, t thick AlGaAs shell, and t thick GaAs supershell. AlGaAs GaAs Sample L [nm] D [nm] t [nm] t [nm] AlGaAs GaAs A 4750 ± 34 138 ± 5 3.5 0.7 B 5190 ± 64 151 ± 5 8.6 1.7 C 4600 ± 52 165 ± 6 11.7 5.8 D 4690 ± 47 197 ± 9 27.7 5.5 Table 1. Characteristic geometric parameters for the four samples together with their standard deviations. The four samples exhibit low fabrication error margins. photo-acoustic technique has been applied to determine the absorption edge of GaAsBi/GaAs NWs . However, the absorption measurements that would provide the detection of the resonant NW behaviour and therefore direct detection of discrete waveguide modes are still lacking. In this work we used the photo-acoustic spec- troscopy (PAS) technique to study absorbance properties of GaAs-AlGaAs heterostructure NWs grown by self-catalyzed technique on lithography-free Si/SiOx patterns . e Th structures under examination are coaxial core-shell-supershell NWs with hexagonal cross section; sche- matic of a single NW is shown in Fig. 1a. NWs are made of GaAs core, surrounded by a thin shell of AlGaAs, around which there is a thin supershell of GaAs; the cross section is shown in Fig. 1b. Characteristic geometric parameters are the NW length L, the overall diameter D, AlGaAs shell thickness t , and GaAs supershell AlGaAs thickness t . We investigate four samples with different NW dimensions, the parameters of which are given in GaAs Table 1. In all work that follows we consider the light normally incident on the cross-section plane, where k is parallel to L. Results e Th NWs were grown by molecular beam epitaxy on p-Si(111) wafers using lithography-free Si/SiOx patterns for defining the nucleation sites. This technique enables fabrication of highly uniform NW ensembles with tailorable NW density (see Methods). In Fig. 2 we show SEM images of the sample A to put into evidence their high quality and uniformity, that also applies to samples B, C and D (Supporting Information, Fig. S1). Since NW distribu- tion does not show any periodical dependence, we can further assume that the response of this ensemble mainly depends on a single NW behaviour rather than on a collective response. We have then obtained the NW size statistics by measuring dimensions of more than 20 NWs per sample from cross-sectional SEM micrographs. The resulting statistics (Table 1) show that the fabrication deviations are small for L and D. The samples also differ 8 −2 7 −2 slightly in the NW density: for samples A, C and D ρ ~ 1 × 10 cm , while ρ ~ 8 × 10 cm . A,C,D B High aspect ratio and high refractive indices of the materials used result in good waveguiding properties along the axes of our NWs. Since GaAs has bandgap wavelength at around 870 nm, material absorption at shorter wavelengths will lead to losses along the propagation, resulting in real component of the transverse wavevector inside NW. This means that the light coupled to these modes will transversely leak out, and they are correspond- ingly called leaky waveguide modes. Their electric field is mainly confined outside NW, contrary to the guided modes. Depending on the symmetry of the incoming electric field, for the TM or TE polarization, these modes can be HE - magnetoelectric (TM -like), or EH - electromagnetic (TE -like), respectively. Here m is the mn mn mn mn m-th order of the corresponding Bessel and Hankel functions that are the solutions of a leaky guided wave in the Scientific Repo R ts | 7: 2833 | DOI:10.1038/s41598-017-02839-1 2 www.nature.com/scientificreports/ Figure 2. (a) SEM edge view of Sample A with NWs of L = (4750 ± 34)nm, D = (138 ± 5)nm. (b) Tilted (30°) SEM image of 3D distribution of Sample A. infinitively long dielectric cylinder, and n corresponds to the n-th zero of these functions. In the case of finite NWs, and the illumination parallel to the NW axis, light scattering at the end facets can provide for the additional coupling where the leaky modes become guided . Such modes result in resonant enhanced absorption that has HE or EH symmetry along NW, and we first numerically investigate their excitation in our samples by simu- mn mn lating the absorption cross section (see Methods and Supporting Information). In Fig. 3 we show the absorption dependence on NW length, using the geometric cross section parameters from the fabrication of Samples A-D. Fig. 3a clearly shows that HE mode for the sample A is excited at around 730 nm, while for the sample B HE resonance moves to around 790 nm (Fig. 3b). This is in agreement with theory because the increase of an effective waveguide diameter red-shifts the resonance of the modes. It is also evident from Fig. 3a,b that the NW length mainly affects the absorption efficiency while the influence on the wavelength of the resonant mode is very small. In Fig. 3c the calculated absorption cross sections for all four samples are shown. Again, the red shift due to the increasing of diameter D from sample A to sample D is clear. Moreover, the geometric parameters of sample D would lead to HE resonance at λ > 870 nm; however, in this range both GaAs and AlGaAs are transparent, therefore sample D, and partially sample C do not show such high absorption for the HE mode. At around 440–500 nm another peak due to the coupling to HE mode arises in 11 12 all four samples, but it has much lower intensity. In Fig. 3d we see that the field confinement corresponds to the symmetry of HE mode in the x-y cross section, while the mode is guided along the wire as shown in the x-z cross section (Fig. 3e). We then experimentally characterize our samples by measuring their absorption by means of the photo-acoustic (PA) technique. PA is a type of photothermal techniques, where absorption of incoming light beam leads to a non-radiative de-excitation process which generates heat, thus changing the thermal state of 30, 31 the sample . If the intensity of the light is modulated in time, a sample in an air-tight chamber heats up and cools down in a cycle and, not having time to expand and contract, corresponding changes in pressure arise. es Th e pressure changes produce an acoustic signal which is then directly converted into an electrical signal by a sensitive microphone. The microphone receives the signal from the sample through the small diameter tunnel (labyrinth) so that the light cannot impinge the microphone directly, thus largely reducing the effects of the scat- tered light (Fig. 4a). By this way we can directly measure the near field absorption, and possibly catch the effects that would be otherwise hidden with other scattering dependent techniques. PA technique has been widely used for the imaging of plasmonic nanoparticles for biomedical applications, dealing with the localized surface plas- 32, 33 28, 34–37 mons . Moreover, it has been recently applied to study NWs ; in ref. 38 we have applied PA technique to demonstrate circular dichroism in GaAs-based NWs asymmetrically hybridized with Au, where three out of six sidewalls were covered with Au, thus leading to the symmetry breaking. However, to our knowledge no work has been performed on investigation of resonant absorption in vertical semiconductor NWs which is essential for the 11 6 development of NW arrays for NW-based photovoltaics and wavelength selective photodetectors . We therefore apply the set-up shown in Fig. 4 to measure the absorption in the spectral range from 300 nm to 1100 nm, where we expect the excitation of HE and HE modes in all the samples (see Methods). 11 12 Scientific Repo R ts | 7: 2833 | DOI:10.1038/s41598-017-02839-1 3 www.nature.com/scientificreports/ Figure 3. (a) Sample A: absorption cross section dependence on L. (b) Sample B: absorption cross section dependence on L. (c) Absorption cross section spectra for samples A–D calculated with the geometric parameters of Table 1. (d) x-y cross section: electric field confinement at HE wavelength (Sample A is used as an example). (e) x-z cross section: electric field confinement at HE wavelength (Sample A is used as an example). In photothermal techniques the thermal diffusion length is inversely proportional to the square of the mod- 39, 40 ulation frequency . This means that with lower frequencies thermal signal takes much higher non-resonant contribution of Si substrate and parasitic (Al)GaAs growth. With the frequency increasing the contribution of the NW surface is higher, so we can see the resonant response which corresponds to the excitation of the discrete modes, as it is depicted in Fig. 5a – for the low frequency (27 Hz) most of the absorption comes from the heat generated in Si substrate (red to blue arrows), while for the highest frequency of 225 Hz the signal originates mainly from the NW absorption. The absorption spectra for three frequencies of Sample B is shown in Fig. 5b. The spectra are normalized to the spectra of the substrate (Supporting information, Figs S5–7). For the lowest frequency of 27 Hz we see the highest contribution of Si substrate, therefore the Si bandgap, and the expected res- onant absorption is hidden by this contribution. Then, at 81 Hz, we start to observe a resonant behavior, with the increased contribution of the parasitic GaAs growth and NWs (GaAs bandgap is seen at 870 nm). Finally, at high frequency of 225 Hz we clearly observe the resonant HE peak which corresponds to the highest contribution of the NW surface that supports this resonance. Similar influence of frequency on the NW PA signal was recently reported for GaAsBi/GaAs core-shell NWs grown on Si . However, no resonant features were observed most probably due to size non-uniformity of the investigated NW ensembles. The contributions of the Si substrate and parasitic growth and NWs on the PA signal were investigated in detail by analyzing reference samples (Supporting information, Fig. S4). We conclude that at high frequency of 225 Hz the non-resonant signal arises mainly from the Si substrate while the contribution of the parasitic layer is very small (Fig. S6). More importantly, the intensity of the non-resonant signal is small compared to the resonant signal arising from the NWs. Therefore, our useful PA signal coming from the resonant response is stable at this frequency, and we continue our measurements keeping f = 225 Hz. mod In Fig. 6 we show the simulated (Fig. 6a) and measured (Fig. 6b) spectra of our samples. We have taken into account the actual NW size distributions of the investigated samples (Table 1) by incorporating a random Gaussian distribution in the simulation; therefore, Fig. 6a shows an average absorption for this distribution gen- erated in L-D parameter space. The absorption efficiency is defined as σ /σ , where σ = D π/4 is the NW abs NW NW Scientific Repo R ts | 7: 2833 | DOI:10.1038/s41598-017-02839-1 4 www.nature.com/scientificreports/ Figure 4. Experimental set-up of the photo-acoustic measurement. Inset (a): Variable volume photoacoustic cell, 1-quartz window, 2-sample, 3-quartz cylinder, 4-microphone, 5-inox cell body, 6-threaded flange, 7-sound labyrinth, 8-O-ring. projected area. We see that these efficiencies at HE resonances are as high as 130 and 150, for Sample A and Sample B, respectively, while for bulk planar materials these are always ≤1. We see that the experiment is in great agreement with theory – namely, the positions of H and H modes almost perfectly match to those of PA 11 12 signals. However, the NW size distributions cannot fully explain the observed PA peak broadening (dashed lines in Fig. 6a show the simulation for a single NW without the actual size distribution). The other factors that may contribute the peak broadening include the interaction between adjacent NWs as well as slightly tapered shape of the NWs. As shown in the Supporting information (Fig. S2), the degree of tapering increases with increasing NW thickness from Sample A to Sample D. e Th refore, we would expect to see significant die ff rences in the peak widths of different samples. Since this is not the case (Fig. 6b), we can exclude the possible influence of NW tapering on the peak broadening. To investigate the collective response of the closely spaced NWs, we have performed FDTD simulations to account for their interaction. The nearest neighbor statistics from top SEM images (Fig. S8) is shown in the Supporting information (Fig. S9). We repeated the simulations for two NWs using these statistics and keeping their other geometric parameters constant (Table 1). We apply again PML in all directions and simulate absorp- tion cross section of the NW. These results along with PA experiment results are then normalized to 1 to show the shape differences, Fig. 7. Results for the single NW are shown as green dashed lines. We see that this two NW simulation fits well with PA spectra for all four samples and that it leads to the broadening with respect to the single NW resonance; therefore, changes in distances between neighbor NWs are one of the reasons for the Scientific Repo R ts | 7: 2833 | DOI:10.1038/s41598-017-02839-1 5 www.nature.com/scientificreports/ Figure 5. (a) Schematic of a different surface / NW contributions for different frequencies: at the lowest 27 Hz the PA signal mainly originates from Si substrate, while at the highest 225 Hz it mainly originates from NW absorption. (b) PA spectra for three different frequencies that correspond to the different contribution of the sample surface for sample B. At the highest frequency 225 Hz we observe the resonant peak corresponding to the excitation of HE11 mode. Figure 6. (a) Simulated average absorption efficiency including the actual NW size distribution for Samples A-D. Single NW simulations included for the sake of comparison. (b) PA spectra for Samples A-D. Scientific Repo R ts | 7: 2833 | DOI:10.1038/s41598-017-02839-1 6 www.nature.com/scientificreports/ Figure 7. FDTD simulations for two NWs compared with PA technique and single NW spectra, and normalized to 1. broadening of the spectra. However, the collective effects of such disordered NW arrays are in general difficult to simulate precisely due to the memory and time consuming simulation sizes. PA technique oer ff s a possibility to directly investigate the absorption properties and therefore catch these effects, which is a big advantage over other techniques. Furthermore, a single NW theory is suitable to predict the behavior of sparse NW arrays ; therefore, we firmly believe that PA can be efficiently used to measure the resonant absorption also in ordered NW arrays. In order to compare PA results with a conventionally used reflection technique, we report on the reflection spectra measurements (Figs S10 and 11) of the samples at normal incidence. In the Supporting information we show that the results are again in agreement with PA technique (Fig. S11) - the positions of reflection dips almost perfectly coincide with the absorption maxima of PA signal. Nevertheless, we point out that for an absolute measurement of the absorption from the reflection, a calibration mirror and an integrating sphere detector would be required to account for scattered fields. Moreover, such characterization usually requires the invasive tech- niques as the removal of NWs from the substrate . On the other hand, the method proposed allows for direct, scattering-insensitive absorption measurement. Discussion Our results have demonstrated that PA technique can be employed as a simple and reliable characteriza- tion technique that measures the enhancement in the absorption due to the excitation of photonic modes in GaAs-AlGaAs-GaAs core-shell-supershell NWs. The measurements evidence a highly efficient absorption enhancement under proper resonant wavelength for H mode and it is in great agreement with numerical sim- ulations. Since this technique directly measures the absorption, no post-processing of the signal is needed like in transmission/reflection and other similar techniques. We also show that the response of our samples is very stable with respect to the fabrication margins of the parameters D and L; we further simulate the response of two NWs the distance of which is taken from the nearest neighbor statistics. We believe that this absence of the uniform- ity of the distance between adjacent NWs is the primary reason for the broadening of the resonances, but they remain pronounced. Present efforts are dedicated to specific improvements of our stable and low-cost PA set-up to allow for the use of both qualitative and quantitative characterization of samples to be used for the realization of many applications of NW such as NW lasers and chirality applications of GaAs-based NWs asymmetrically covered with Au. Methods NW fabrication. e Th GaAs core was first grown by self-catalyzed growth mode. Then the Ga catalyst droplet was consumed in As2-flux in order to terminate axial growth. The Al Ga As shell and GaAs supershell were 0.3 0.7 then grown around the NW core using growth conditions that promote radial growth. The details of the Si/SiOx Scientific Repo R ts | 7: 2833 | DOI:10.1038/s41598-017-02839-1 7 www.nature.com/scientificreports/ pattern fabrication and NW growth are explained in more detail in and in Supporting information (1-2), which includes also the description of the shell layer growth and characterization of the coaxial heterostructure (Fig. S2-S3 and Table S1). Numerical calculations. We have used Lumerical Finite Difference Time Domain (FDTD) solver to sim- ulate the absorption cross section spectra of a single GaAs-AlGaAs-GaAs NW, by applying perfectly matched layers (PML) in all directions. A single NW is excited by total-field scattered-field source (TFSF) that is suitable for simulations of the absorption cross section in a box surrounding the NW (Supporting information 6). PA absorption. The samples are shined from the air side by a Xenon arc lamp source followed by a mono- chromator, which provides the spectral range from 300 nm to 1100 nm. This source is modulated by a mechanical chopper whose frequency choice sets the contribution of the NW surface to the overall absorption. The output of the microphone pre-amplifier (PA) is connected with the input of the lock-in amplifier and analyses the signal with respect to the modulated frequency of the light source. The main element of the cell is a movable transparent quartz cylinder, with two optically polished faces, which oer ff s some advantages: its movement along the cylinder axis direction changes the distance between the sample surface and the window, so that we can choose the opti- mum volume of the cell. All the samples are shined under a normal incidence, but our set-up is adaptable also for incidence angle and polarization scan. References 1. Cao, L., White, J. S., Park, J.-S., Schuller, J. A., Clemens, B. M. & Brongersma, M. L. Engineering light absorption in semiconductor nanowire devices. Nat. Mater. 8, 643–647 (2009). 2. Mayer, B. et al. Lasing from individual GaAs-AlGaAs core-shell nanowires up to room temperature. Nat. Commun. 4, 2931 (2013). 3. Mayer, B. et al. Monolithically Integrated High-beta Nanowire Lasers on Silicon. Nano Lett. 16, 152–156 (2016). 4. Fountaine, K. T., Whitney, W. S. & Atwater, H. A. Resonant absorption in semiconductor nanowires and nanowire arrays: Relating leaky waveguide modes to Bloch photonic crystal modes. J. Appl. Phys. 116, 153106 (2014). 5. Abujetas, D. R., Paniagua-Domínguez, R. & Sánchez-Gil, J. A. Unraveling the janus role of mie resonances and leaky/guided modes in semiconductor nanowire absorption for enhanced light harvesting. ACS Photonics 2, 921–929 (2015). 6. Mokkapati, S., Saxena, D., Tan, H. H. & Jagadish, C. Optical design of nanowire absorbers for wavelength selective photodetectors. Sci. Rep. 5, 15539 (2015). 7. Alizadeh, M. H. & Reinhard, B. M. Emergence of transverse spin in optical modes of semiconductor nanowires. Opt. Express 24, 8471–8479 (2016). 8. Wang, J., Gudiksen, M. S., Duan, X., Cui, Y. & Lieber, C. M. Highly polarized photoluminescence and photodetection from single indium phosphide nanowires. Science 293, 1455–1457 (2001). 9. Tian, B., Kempa, T. J. & Lieber, C. M. Single nanowire photovoltaics. Chem. Soc. Rev. 38, 16–24 (2009). 10. Muskens, O. L., Gómez Rivas, J., Algra, R. E., Bakkers, E. P. A. M. & Lagendijk, A. Design of light scattering in nanowire materials for photovoltaic applications. Nano Lett. 8, 2638–2642 (2008). 11. Wallentin, J. et al. InP nanowire array solar cells achieving 13.8% efficiency by exceeding the ray optics limit. Science 339, 1057–1060 (2013). 12. Bao, J., Zimmler, M. A., Capasso, F., Wang, X. & Ren, Z. F. Broadband ZnO single-nanowire light-emitting diode. Nano Lett. 6, 1719–17222 (2006). 13. Huang, M. H. et al. Room-temperature ultraviolet nanowire nanolasers. Science 292, 1897–1899 (2001). 14. Greytak, A. B., Barrelet, C. J., Li, Y. & Lieber, C. M. Semiconductor nanowire laser and nanowire waveguide electro-optic modulators. Appl. Phys. Lett. 87, 151103 (2005). 15. Ahn, Y., Dunning, J. & Park, J. Scanning Photocurrent Imaging and Electronic Band Studies in Silicon Nanowire Field Effect Transistors. Nano Lett. 5, 1367–1370 (2005). 16. Standing, A. et al. Efficient water reduction with gallium phosphide nanowires. Nat. Commun. 6, 7824 (2015). 17. Åberg, I. et al. A GaAs Nanowire Array Solar Cell With 15.3% Efficiency at 1 Sun. IEEE J. Photovoltaics 6, 185 (2016). 18. Bautista, G. et al. Second-harmonic generation imaging of semiconductor nanowires with focused vector beams. Nano Lett. 15, 1564–1569 (2015). 19. Ramezani, M. et al. Hybrid Semiconductor Nanowire–Metallic Yagi-Uda Antennas. Nano Lett. 15, 4889–4895 (2015). 20. Sidiropoulos, T. P. H. et al. Ultrafast plasmonic nanowire lasers near the surface plasmon frequency. Nature Phys. 10, 870–876 (2014). 21. Wu, X. et al. Hybrid photon-plasmon nanowire lasers. Nano Lett. 13(11), 5654–5659 (2013). 22. Oulton, R. F. et al. Plasmon lasers at deep subwavelength scale. Nature 461, 629–632 (2009). 23. Najar, A., Charrier, J., Pirasteh, P. & Sougrat, R. Ultra-low reflection porous silicon nanowires for solar cell applications. Opt Express 20, 16861–16870 (2012). 24. unicThh, S. et al. Photocurrent and photoconductance properties of a GaAs nanowire. Appl. Phys. Lett. 95, 83111 (2009). 25. Jahn, U. et al. Luminescence of GaAs nanowires consisting of wurtzite and zinc-blende segments. Phys. Rev. B 85, 045323 (2012). 26. Vainorius, N. et al. Observation of type-II recombination in single wurtzite/zinc-blende GaAs heterojunction nanowires. Phys. Rev. B 89, 165423 (2014). 27. Arab, S., Yao, M., Zhou, C., Dapkus, P. D. & Cronin, S. B. Doping concentration dependence of the photoluminescence spectra of n-type GaAs nanowires. Appl. Phys. Lett. 108, 182106 (2016). 28. Zelewski, S. et al. Photoacoustic spectroscopy of absorption edge for GaAsBi/GaAs nanowires grown on Si substrate. Appl. Phys. Lett. 109, 182106 (2016). 29. Hakkarainen, T. V., Schramm, A., Mäkelä, J., Laukkanen, P. & Guina, M. Lithography-free oxide patterns as templates for self- catalyzed growth of highly uniform GaAs nanowires on Si(111). Nanotechnology 26, 275301 (2015). 30. Inagaki, T., Kagami, K. & Arakawa, E. T. Photoacoustic observation of nonradiative decay of surface plasmons in silver. Phys. Rev. B 24, 3644R (1981). 31. Inagaki, T., Kagami, K. & Arakawa, E. T. Photoacoustic study of surface plasmons in metals. Appl. Opt. 21, 949 (1982). 32. Petronijevic, E., Leahu, G., Mussi, V., Sibilia, C. & Bovino, F. A. Photoacoustic technique for the characterization of plasmonic properties of 2D periodic arrays of gold nanoholes. AIP Adv. 7, 025210 (2017). 33. El-Brolossy, T. A. et al. Shape and size dependence of the surface plasmon resonance of gold nanoparticles studied by Photoacoustic technique. Eur. Phys. J. Spec. Top. 153, 361–364 (2008). 34. Li Voti, R. et al. Photoacoustic Characterization of Randomly Oriented Silver Nanowire Films. Int. J. Thermophys. 36, 1342–1348 (2015). 35. Kuthirummal, N., Reppert, J., Dihel, B. & Rao, A. M. Synthesis and optical spectroscopic studies of semiconducting cadmium sulfide nanowires. Appl. Opt. 48, 2842–2846 (2009). Scientific Repo R ts | 7: 2833 | DOI:10.1038/s41598-017-02839-1 8 www.nature.com/scientificreports/ 36. Larciprete, M. C. et al. Infrared properties of randomly oriented silver nanowires. J. Appl. Phys. 112, 083503 (2012). 37. Belardini, A. et al. Chiral light intrinsically couples to extrinsic/pseudo-chiral metasurfaces made of tilted gold nanowires. Sci. Rep. 6, 31796 (2016). 38. Leahu, G. et al. Evidence of Optical Circular Dichroism in GaAs-Based Nanowires Partially Covered with Gold. Adv. Opt. Mat. 2017, 1601063, doi:10.1002/adom.201601063 (2017). 39. Ma, T., Munidasa, M. & Mandelis, A. Photoacoustic frequency‐domain depth profilometry of surface‐layer inhomogeneities: Application to laser processed steels. J. Appl. Phys. 71, 6029 (1992). 40. Guo, X., Mandelis, A. & Zinman, B. Noninvasive glucose detection in human skin using wavelength modulated differential laser photothermal radiometry. Biomed. Opt. Express 3, 3012–3021 (2012). 41. Fountaine, K. T., Cheng, W., Bukowsky, C. R. & Atwater, H. A. Near-Unity Unselective Absorption in Sparse InP Nanowire Arrays. ACS Photonics 3, 1826–1832 (2016). Acknowledgements This work made use of Aalto University Nanomicroscopy Center (Aalto-NMC) facilities. Funding from the Academy of Finland Project NESP (decision number 294630) is acknowledged. Author Contributions Photo-acoustic experiments were planned by A.B. and G.L. and executed by G.L. Sample design and fabrication were done T.H. and E.K. Theoretical work and data fitting were done by E.P. and M.C. The results were discussed by all authors and all authors contributed to the manuscript. Additional Information Supplementary information accompanies this paper at doi:10.1038/s41598-017-02839-1 Competing Interests: The authors declare that they have no competing interests. Publisher's note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Cre- ative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not per- mitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. © The Author(s) 2017 Scientific Repo R ts | 7: 2833 | DOI:10.1038/s41598-017-02839-1 9
Scientific Reports – Springer Journals
Published: Jun 6, 2017
It’s your single place to instantly
discover and read the research
that matters to you.
Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.
All for just $49/month
Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly
Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.
Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.
Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.
All the latest content is available, no embargo periods.
“Hi guys, I cannot tell you how much I love this resource. Incredible. I really believe you've hit the nail on the head with this site in regards to solving the research-purchase issue.”Daniel C.
“Whoa! It’s like Spotify but for academic articles.”@Phil_Robichaud
“I must say, @deepdyve is a fabulous solution to the independent researcher's problem of #access to #information.”@deepthiw
“My last article couldn't be possible without the platform @deepdyve that makes journal papers cheaper.”@JoseServera