Palladium-catalyzed regioselective introduction of chalcogen moieties into porphyrin bearing an ethynyl group

Palladium-catalyzed regioselective introduction of chalcogen moieties into porphyrin bearing an... In the field of materials science, π-conjugated molecules bearing a group 16 heteroatom are of great importance. Sulfur or selenium containing porphyrins were successfully synthesized using the transition-metal-catalyzed reaction with diphenyl dichalcogenides. NMR studies indicated the preferential formation of the (Z)-isomer. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Palladium-catalyzed regioselective introduction of chalcogen moieties into porphyrin bearing an ethynyl group

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Publisher
Springer Netherlands
Copyright
Copyright © 2009 by Springer Science+Business Media BV
Subject
Chemistry; Inorganic Chemistry ; Physical Chemistry ; Catalysis
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-009-0087-8
Publisher site
See Article on Publisher Site

Abstract

In the field of materials science, π-conjugated molecules bearing a group 16 heteroatom are of great importance. Sulfur or selenium containing porphyrins were successfully synthesized using the transition-metal-catalyzed reaction with diphenyl dichalcogenides. NMR studies indicated the preferential formation of the (Z)-isomer.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Oct 10, 2009

References

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