μ-Oxo-Bis[(Bromo)Tri-m-Tolylantimony]: Synthesis and Structure

μ-Oxo-Bis[(Bromo)Tri-m-Tolylantimony]: Synthesis and Structure μ-Oxo-bis[(bromo)tri-m-tolylantimony] was synthesized by the reaction of tri-m-tolylstibine with hydrobromic acid in ether in the presence of hydrogen peroxide. The complex was structurally characterized by X-ray diffraction analysis. The coordination polyhedron of the Sb atoms is a distorted trigonal bipyramid with the bromine and the bridging O atoms in the axial positions. The Sb(1)–C(Ph) distances vary from 2.085(9) to 2.111(8) Å. The Sb(1)–Br(1) and Sb(2)–Br(2) bond lengths are 2.739(2) and 2.735(2) Å, respectively; the Sb–Obr distances measure 1.949(1) Å. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

μ-Oxo-Bis[(Bromo)Tri-m-Tolylantimony]: Synthesis and Structure

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Publisher
Kluwer Academic Publishers-Plenum Publishers
Copyright
Copyright © 2002 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Physical Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1023/A:1016297110877
Publisher site
See Article on Publisher Site

Abstract

μ-Oxo-bis[(bromo)tri-m-tolylantimony] was synthesized by the reaction of tri-m-tolylstibine with hydrobromic acid in ether in the presence of hydrogen peroxide. The complex was structurally characterized by X-ray diffraction analysis. The coordination polyhedron of the Sb atoms is a distorted trigonal bipyramid with the bromine and the bridging O atoms in the axial positions. The Sb(1)–C(Ph) distances vary from 2.085(9) to 2.111(8) Å. The Sb(1)–Br(1) and Sb(2)–Br(2) bond lengths are 2.739(2) and 2.735(2) Å, respectively; the Sb–Obr distances measure 1.949(1) Å.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Oct 13, 2004

References

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