Oxidation of aromatic hydrocarbons with H2O2 catalyzed by a nano-scale tubular aluminosilicate, Fe-containing imogolite

Oxidation of aromatic hydrocarbons with H2O2 catalyzed by a nano-scale tubular aluminosilicate,... Imogolite is a nano-scale tubular clay mineral with the typical chemical composition (OH)3Al2O3SiOH. The Fe-containing imogolite was synthesized from FeCl3, AlCl3 and Na4SiO4 aqueous solutions. The fibrous morphology observed by AFM in this sample is similar to that of synthetic imogolite. In the catalytic oxidation of aromatic hydrocarbon compounds such as benzene, phenol and chrolobenzene, the aromatic ring was oxidized. When the side-chain is a hydrocarbon group such as methyl, both benzene ring and the side-chain group were oxidized. It was found that the side-chain group was preferentially oxidized. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Oxidation of aromatic hydrocarbons with H2O2 catalyzed by a nano-scale tubular aluminosilicate, Fe-containing imogolite

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Publisher
Springer Netherlands
Copyright
Copyright © 2008 by Springer
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/BF03036925
Publisher site
See Article on Publisher Site

Abstract

Imogolite is a nano-scale tubular clay mineral with the typical chemical composition (OH)3Al2O3SiOH. The Fe-containing imogolite was synthesized from FeCl3, AlCl3 and Na4SiO4 aqueous solutions. The fibrous morphology observed by AFM in this sample is similar to that of synthetic imogolite. In the catalytic oxidation of aromatic hydrocarbon compounds such as benzene, phenol and chrolobenzene, the aromatic ring was oxidized. When the side-chain is a hydrocarbon group such as methyl, both benzene ring and the side-chain group were oxidized. It was found that the side-chain group was preferentially oxidized.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Apr 15, 2009

References

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