Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

Onion-like carbon microspheres as long-life anodes materials for Na-ion batteries

Onion-like carbon microspheres as long-life anodes materials for Na-ion batteries Room-temperature Na-ion batteries have been widely used as promising energy storage systems for large-scale storage due to the nature abundance and low cost of Na. However, the search for an anode with appropriate Na storage and high structural stability still remains challenging. In this work, the carbon microsphere films-coated Ni foam is prepared by a simple chemical vapor deposition method and is used as a novel anode for the long-lifespan Na-ion batteries. These carbon microspheres possess special onion-like structures that enhance the Na-ions intercalation and exhibit excellent Na storage properties. In addition, directly coating the carbon microsphere films on Ni foam current collectors without binders and conductive additives results in an integrated electrode structure, which avoids the undesirable interfaces and reduces the packaging volume. Compared to the common used hard carbon anode with long discharge plateau and short lifespan, this integrated electrode exhibits a slope discharge profile with higher security and demonstrates a long lifespan of 700 cycles with a high capacity retention of 83%. Furthermore, the storage mechanism of sodium ion is also investigated in detail by ex situ Raman, X-ray diffraction and nuclear magnetic resonance techniques in this study. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Materials Science Springer Journals

Onion-like carbon microspheres as long-life anodes materials for Na-ion batteries

Download PDF
11 pages

Loading next page...
 
/lp/springer_journal/onion-like-carbon-microspheres-as-long-life-anodes-materials-for-na-uiYbxkgle0
Publisher
Springer Journals
Copyright
Copyright © 2018 by Springer Science+Business Media, LLC, part of Springer Nature
Subject
Materials Science; Materials Science, general; Characterization and Evaluation of Materials; Polymer Sciences; Continuum Mechanics and Mechanics of Materials; Crystallography and Scattering Methods; Classical Mechanics
ISSN
0022-2461
eISSN
1573-4803
DOI
10.1007/s10853-018-2515-x
Publisher site
See Article on Publisher Site

Abstract

Room-temperature Na-ion batteries have been widely used as promising energy storage systems for large-scale storage due to the nature abundance and low cost of Na. However, the search for an anode with appropriate Na storage and high structural stability still remains challenging. In this work, the carbon microsphere films-coated Ni foam is prepared by a simple chemical vapor deposition method and is used as a novel anode for the long-lifespan Na-ion batteries. These carbon microspheres possess special onion-like structures that enhance the Na-ions intercalation and exhibit excellent Na storage properties. In addition, directly coating the carbon microsphere films on Ni foam current collectors without binders and conductive additives results in an integrated electrode structure, which avoids the undesirable interfaces and reduces the packaging volume. Compared to the common used hard carbon anode with long discharge plateau and short lifespan, this integrated electrode exhibits a slope discharge profile with higher security and demonstrates a long lifespan of 700 cycles with a high capacity retention of 83%. Furthermore, the storage mechanism of sodium ion is also investigated in detail by ex situ Raman, X-ray diffraction and nuclear magnetic resonance techniques in this study.

Journal

Journal of Materials Science – Springer Journals

Published: Jun 6, 2018

References

  • The Li-ion rechargeable battery: a perspective
    Goodenough, JB; Park, K-S
  • Building better batteries
    Armand, M; Tarascon, J-M
  • Multi-shelled LiMn2O4 hollow microspheres as superior cathode materials for lithium-ion batteries
    Wang, F; Wang, J; Ren, H; Tang, H; Yu, R; Wang, D
  • Effect of fiber orientation in gelled poly (vinylidene fluoride) electrospun membranes for Li-ion battery applications
    Costa, CM; Nunes-Pereira, J; Sencadas, V; Silva, MM; Lanceros-Méndez, S
  • Sodium-ion batteries
    Slater, MD; Kim, D; Lee, E; Johnson, CS
  • A zero-strain insertion cathode material of nickel ferricyanide for sodium-ion batteries
    You, Y; Wu, X-L; Yin, Y-X; Guo, Y-G
  • Sodium ion batteries: free-standing nitrogen-doped carbon nanofiber films: integrated electrodes for sodium-ion batteries with ultralong cycle life and superior rate capability
    Wang, S; Xia, L; Yu, L; Zhang, L; Wang, H; Lou, XWD
  • Engraving copper foil to give large-scale binder-free porous Cuo arrays for a high-performance sodium-ion battery anode
    Yuan, S; Huang, XL; Ma, DL; Wang, HG; Meng, FZ; Zhang, XB
  • Nanostructured polystyrene/polyaniline/graphene hybrid materials for electrochemical supercapacitor and Na-ion battery applications
    Chen, J; Liu, Y; Li, W; Wu, C; Xu, L; Yang, H
  • Understanding the structural evolution and redox mechanism of a NaFeO2–NaCoO2 solid solution for sodium-ion batteries
    Kubota, K; Asari, T; Yoshida, H; Yaabuuchi, N; Shiiba, H; Nakayama, M; Komaba, S
  • Suppressing the P2–O2 phase transition of Na0. 67Mn0. 67Ni0. 33O2 by magnesium substitution for improved sodium-ion batteries
    Wang, PF; You, Y; Yin, YX; Wang, YS; Wan, LJ; Gu, L; Guo, YG
  • Hierarchical carbon framework wrapped Na3V2(PO4)3 as a superior high-rate and extended lifespan cathode for sodium-ion batteries
    Fang, Y; Xiao, L; Ai, X; Cao, Y; Yang, H
  • Carbon-Coated Na3V2(PO4)3 embedded in porous carbon matrix: an ultrafast na-storage cathode with the potential of outperforming Li cathodes
    Zhu, C; Song, K; Aken, PA; Maier, J; Yu, Y
  • Large-scale synthesis of NaNi1/3Fe1/3Mn1/3O2 as high performance cathode materials for sodium ion batteries
    Wang, H; Liao, X-Z; Yang, Y; Yan, X; He, Y-S; Ma, Z-F
  • Subzero-temperature cathode for a sodium-ion battery
    You, Y; Yao, HR; Xin, S; Yin, YX; Zuo, TT; Yang, CP; Guo, YG; Cui, Y; Wan, LJ; Goodenough, JB
  • Improving the electrochemical performance of Na3V2(PO4)3 cathode in sodium ion batteries through Ce/V substitution based on rational design and synthesis optimization
    Zheng, Q; Yi, H; Liu, W; Li, X; Zhang, H
  • Graphene quantum dots coated VO2 arrays for highly durable electrodes for Li and Na ion batteries
    Chao, D; Zhu, C; Xia, X; Liu, J; Zhang, X; Wang, J; Liang, P; Lin, J; Zhang, H; Shen, ZX; Fan, HJ
  • Carbon quantum dot surface-engineered VO2 interwoven nanowires: a flexible cathode material for lithium and sodium ion batteries
    Balogun, M-S; Luo, Y; Lyu, F; Wang, F; Yang, H; Li, H; Liang, C; Huang, M; Huang, Y; Tong, Y
  • SnSb@Carbon nanocable anchored on graphene sheets for sodium ion batteries
    Li, L; Seng, KH; Li, D; Xia, Y; Liu, HK; Guo, Z
  • A zero-strain layered metal oxide as the negative electrode for long-life sodium-ion batteries
    Wang, Y; Yu, X; Xu, S; Bai, J; Xiao, R; Hu, Y-S; Li, H; Yang, X-Q; Chen, L; Huang, X
  • High capacity anode materials for rechargeable sodium-ion batteries
    Stevens, D; Dahn, J
  • Monolithic hierarchical carbon assemblies embedded with mesoporous NaTi2(PO4)3 nanocrystals for flexible high-performance sodium anodes
    Xu, G; Li, Z; Wei, X; Yang, L; Chu, PK
  • Highly reversible sodium-ion storage in NaTi2(PO4)3/C composite nanofibers
    Li, M; Liu, L; Wang, P; Li, J; Leng, Q; Cao, G
  • Rose-like N-Doped porous carbon for advanced sodium storage
    Zhao, G; Zou, G; Qiu, X; Li, S; Guo, T; Hou, H; Ji, X
  • Tin-coated viral nanoforests as sodium-ion battery anodes
    Liu, Y; Xu, Y; Zhu, Y; Culver, JN; Lundgren, CA; Xu, K; Wang, C
  • Spherical nano-Sb@C composite as a high-rate and ultra-stable anode material for sodium-ion batteries
    Zhang, N; Liu, Y; Lu, Y; Han, X; Cheng, F; Chen, J
  • In situ synthesis of chemically bonded NaTi2(PO4)3/rGO 2D nanocomposite for high-rate sodium-ion batteries
    Roh, H-K; Kim, H-K; Kim, M-S; Kim, D-H; Chung, KY; Roh, KC; Kim, K-B
  • A review of carbon materials and their composites with alloy metals for sodium ion battery anodes
    Balogun, M-S; Luo, Y; Qiu, W; Liu, P; Tong, Y
  • Electrochemical intercalation of sodium in graphite
    Ge, P; Fouletier, M
  • Sodium ion insertion in hollow carbon nanowires for battery applications
    Cao, Y; Xiao, L; Sushko, ML; Wang, W; Schwenzer, B; Xiao, J; Nie, Z; Saraf, LV; Yang, Z; Liu, J
  • Insertion electrode materials for rechargeable lithium batteries
    Winter, M; Besenhard, JO; Spahr, ME; Novak, P
  • Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
    Pan, H; Hu, Y-S; Chen, L
  • Superior storage performance of carbon nanosprings as anode materials for lithium-ion batteries
    Wu, X-L; Liu, Q; Guo, Y-G; Song, W-G
  • Nanographene-constructed hollow carbon spheres and their favorable electroactivity with respect to lithium storage
    Yang, S; Feng, X; Zhi, L; Cao, Q; Maier, J; Müllen, K
  • A sandwich-like hierarchically porous carbon/graphene composite as a high-performance anode material for sodium-ion batteries
    Yan, Y; Yin, YX; Guo, YG; Wan, LJ
  • A high performance sulfur-doped disordered carbon anode for sodium ion batteries
    Li, W; Zhou, M; Li, H; Wang, K; Cheng, S; Jiang, K
  • Stable Li plating/stripping electrochemistry realized by a hybrid li reservoir in spherical carbon granules with 3D conducting skeletons
    Ye, H; Xin, S; Yin, Y-X; Li, J-Y; Guo, Y-G; Wan, L-J
  • Hollow carbon nanospheres with superior rate capability for sodium-based batteries
    Tang, K; Fu, L; White, RJ; Yu, L; Titirici, MM; Antonietti, M; Maier, J
  • Highly disordered carbon as a superior anode material for room-temperature sodium-ion batteries
    Zhou, X; Guo, YG
  • Mechanisms for lithium insertion in carbonaceous materials
    Dahn, JR; Zheng, T; Liu, Y; Xue, J
  • Nonaqueous liquid electrolytes for lithium-based rechargeable batteries
    Xu, K
  • In situ raman spectroscopy of insertion electrodes for lithium-ion batteries and supercapacitors: first cycle effects
    Hardwick, LJ; Ruch, PW; Hahn, M; Scheifele, W; Kötz, R; Novák, P
  • Electrochemical Na insertion and solid electrolyte interphase for hard-carbon electrodes and application to Na-ion batteries
    Komaba, S; Murata, W; Ishikawa, T; Yabuuchi, N; Ozeki, T; Nakayama, T; Ogata, A; Gotoh, K; Fujiwara, K
  • Carbon microspheres obtained from resorcinol–formaldehyde as high-capacity electrodes for sodium-ion batteries
    Alcántara, R; Lavela, P; Ortiz, GF; Tirado, JL
  • 11B, 23Na, 27Al, and 19F NMR study of solid and molten Na3AlF6–Na2B4O7
    Bessada, C; Anghel, EM
  • NMR study for electrochemically inserted Na in hard carbon electrode of sodium ion battery
    Gotoh, K; Ishikawa, T; Shimadzu, S; Yabuuchi, N; Komaba, S; Takeda, K; Goto, A; Deguchi, K; Ohki, S; Hashi, K
  • High rate and stable cycling of lithium metal anode
    Qian, J; Henderson, WA; Xu, W; Bhattacharya, P; Engelhard, M; Borodin, O; Zhang, J-G
  • A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions
    Aurbach, D; Zinigrad, E; Cohen, Y; Teller, H
  • Review of selected electrode-solution interactions which determine the performance of Li and Li ion batteries
    Aurbach, D
  • Synergism of Al-containing solid electrolyte interphase layer and Al-based colloidal particles for stable lithium anode
    Ye, H; Yin, Y-X; Zhang, S-F; Shi, Y; Liu, L; Zeng, X-X; Wen, R; Guo, Y-G; Wan, L-J
  • Ultrathin two-dimensional atomic crystals as stable interfacial layer for improvement of lithium metal anode
    Yan, K; Lee, HW; Gao, T; Zheng, G; Yao, H; Wang, H; Lu, Z; Zhou, Y; Liang, Z; Liu, Z; Chu, S; Cui, Y