On reasons for varied reversibility of different kinds of nickel oxide electrodes in alkaline-zincate electrolytes

On reasons for varied reversibility of different kinds of nickel oxide electrodes in... Significant difference between the working capacities in zincate electrolytes of reversible nickel oxide electrodes of two types, lamellar with a graphite additive and metal-ceramic, was noted. It was demonstrated that the electrochemical reversibility of the active substance of nickel oxide electrodes is strongly impaired in the simultaneous presence of the carbon (graphite) component and oxygen in the reacting electrodes and zincate in the electrolyte. In operation of electrodes of this kind in alkaline nickel-zinc batteries, the oxygen-involving process is of side (parallel) nature. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

On reasons for varied reversibility of different kinds of nickel oxide electrodes in alkaline-zincate electrolytes

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2013 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427213010059
Publisher site
See Article on Publisher Site

Abstract

Significant difference between the working capacities in zincate electrolytes of reversible nickel oxide electrodes of two types, lamellar with a graphite additive and metal-ceramic, was noted. It was demonstrated that the electrochemical reversibility of the active substance of nickel oxide electrodes is strongly impaired in the simultaneous presence of the carbon (graphite) component and oxygen in the reacting electrodes and zincate in the electrolyte. In operation of electrodes of this kind in alkaline nickel-zinc batteries, the oxygen-involving process is of side (parallel) nature.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Feb 19, 2013

References

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