On Assessment of the Thermodynamic Consistency of Data on Liquid-Vapor Equilibrium

On Assessment of the Thermodynamic Consistency of Data on Liquid-Vapor Equilibrium A new method for assessment of the thermodynamic consistency of binary isothermal data on the liquid-vapor equilibrium by calculating the Redlich-Kiester integral with account of how the pressure of phase coexistence depends on the vapor composition is suggested. The Maple 8 software is used to compare the values of the integral, other characteristics calculated for systems with varied nature of departures from the Raoult law. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

On Assessment of the Thermodynamic Consistency of Data on Liquid-Vapor Equilibrium

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Publisher
Kluwer Academic Publishers-Plenum Publishers
Copyright
Copyright © 2004 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1023/B:RJAC.0000044111.83007.77
Publisher site
See Article on Publisher Site

Abstract

A new method for assessment of the thermodynamic consistency of binary isothermal data on the liquid-vapor equilibrium by calculating the Redlich-Kiester integral with account of how the pressure of phase coexistence depends on the vapor composition is suggested. The Maple 8 software is used to compare the values of the integral, other characteristics calculated for systems with varied nature of departures from the Raoult law.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Dec 11, 2004

References

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