A new method for assessment of the thermodynamic consistency of binary isothermal data on the liquid-vapor equilibrium by calculating the Redlich-Kiester integral with account of how the pressure of phase coexistence depends on the vapor composition is suggested. The Maple 8 software is used to compare the values of the integral, other characteristics calculated for systems with varied nature of departures from the Raoult law.
Russian Journal of Applied Chemistry – Springer Journals
Published: Dec 11, 2004
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