Nitration of phenol in 1,4-dioxane

Nitration of phenol in 1,4-dioxane The nitration of phenol with excess nitric acid in aqueous dioxane, in contrast to the nitration in aqueous ethanol, yields exclusively 2,4-dintrophenol, whereas at equimolar ratio of phenol and nitric acid the major reaction products are mononitrophenols (99%), among which the p-isomer prevails. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals
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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S10704272150110075
Publisher site
See Article on Publisher Site

Abstract

The nitration of phenol with excess nitric acid in aqueous dioxane, in contrast to the nitration in aqueous ethanol, yields exclusively 2,4-dintrophenol, whereas at equimolar ratio of phenol and nitric acid the major reaction products are mononitrophenols (99%), among which the p-isomer prevails.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Feb 17, 2016

References

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