New method for pyrolysis of pyridine is suggested. One of yielded by the method is a new type of heteroatomic molecules in the form of exohedrally hydrogenated and hydroxylated azafullerenes (C35N5)H9, (C45N5) (OH)3H14, and (C49N11)(OH)5H18. C60 fullerene, its hydrides, and new carbon molecules, such as quasi-fullerene C48 and C3-C15, are detected for the first time in pyridine pyrolysis products by mass-spectral analysis. Hydrides of the carbon molecules are synthesized for the first time without using fullerene.
Russian Journal of Applied Chemistry – Springer Journals
Published: Mar 15, 2013
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