New composite catalysts for the synthesis of acetonitrile from ethanol and ammonia, prepared using calcium aluminates (Talyum)

New composite catalysts for the synthesis of acetonitrile from ethanol and ammonia, prepared... Experiments on direct synthesis of acetonitrile from ethanol, ammonia, and hydrogen at 513–573 K in the presence of new Cu-, Cu–Zn–(Zr)-, and Cu–Mg-containing composite catalysts prepared using calcium aluminates (Talyum, technical-grade calcium aluminate) were performed The following results were reached: ethanol conversion 96.0–99.0%, selectivity with respect to acetonitrile 99.0%, and acetonitrile output exceeding the reported level by a factor of 1.2–1.4. The new technology can be implemented in industry. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

New composite catalysts for the synthesis of acetonitrile from ethanol and ammonia, prepared using calcium aluminates (Talyum)

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Publisher
Pleiades Publishing
Copyright
Copyright © 2016 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427216030113
Publisher site
See Article on Publisher Site

Abstract

Experiments on direct synthesis of acetonitrile from ethanol, ammonia, and hydrogen at 513–573 K in the presence of new Cu-, Cu–Zn–(Zr)-, and Cu–Mg-containing composite catalysts prepared using calcium aluminates (Talyum, technical-grade calcium aluminate) were performed The following results were reached: ethanol conversion 96.0–99.0%, selectivity with respect to acetonitrile 99.0%, and acetonitrile output exceeding the reported level by a factor of 1.2–1.4. The new technology can be implemented in industry.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jun 15, 2016

References

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