New cluster-type rhodium selenochlorides in oxidative carbonylation of methane

New cluster-type rhodium selenochlorides in oxidative carbonylation of methane New rhodium selenochlorides Rh4Se16Cl10 and Rh4Se18Cl10 whose structure is based on the cluster “cubane” [Rh4(μ3-Se)4] and products of their thermal transformations were obtained. The catalytic properties of the compounds on various carbon and silica supports in oxidative carbonylation of methane in the gas phase and their dependence on the catalyst preparation technique, type of support, and size of its nanopores were analyzed. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

New cluster-type rhodium selenochlorides in oxidative carbonylation of methane

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Publisher
Nauka/Interperiodica
Copyright
Copyright © 2007 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S107042720702005X
Publisher site
See Article on Publisher Site

Abstract

New rhodium selenochlorides Rh4Se16Cl10 and Rh4Se18Cl10 whose structure is based on the cluster “cubane” [Rh4(μ3-Se)4] and products of their thermal transformations were obtained. The catalytic properties of the compounds on various carbon and silica supports in oxidative carbonylation of methane in the gas phase and their dependence on the catalyst preparation technique, type of support, and size of its nanopores were analyzed.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Mar 20, 2007

References

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