New rhodium selenochlorides Rh4Se16Cl10 and Rh4Se18Cl10 whose structure is based on the cluster “cubane” [Rh4(μ3-Se)4] and products of their thermal transformations were obtained. The catalytic properties of the compounds on various carbon and silica supports in oxidative carbonylation of methane in the gas phase and their dependence on the catalyst preparation technique, type of support, and size of its nanopores were analyzed.
Russian Journal of Applied Chemistry – Springer Journals
Published: Mar 20, 2007
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