The zeolite minerals characterized with hydrated aluminosilicates, negative ionic charge and 3D framework structure are well known for purifying the groundwater occurring in basaltic aquifer systems. However, the filtering mechanism at in situ field conditions is a complex process, which is rarely studied, and hence, it needs to be demonstrated. This paper explores the mechanism of hydrochemical processes and evolution of natural zeolites associated with basaltic rock to enhance groundwater quality. We present the hydrochemical findings and evolution processes derived from 46 groundwater samples (Nt = 46) belong to zeolitic (Nz = 25) and non-zeolitic (Nnz = 21) zones of a micro-watershed (4.4 km2) beset over basaltic terrain, Deccan Volcanic Province (DVP), India. The groundwater samples collected for one hydrological cycle (pre- and post-monsoons) are examined for major ion chemistry to determine the aqueous solution mechanism and ion-exchange process occurred in zeolitic and non-zeolitic zones. Further, the hydrochemical parameters are appraised by means of dominancy of ions, rock–water interactions, silicate weathering, chloro-alkaline indices, cation-exchange bivariate plots and the mechanism controlling groundwater chemistry. The results show that: 1) the purifying efficiency of zeolites for total ionic strength is observed as 63.85 and 68.58% during pre- and post-monsoons, respectively, 2) the significant reduction (36.51%) in total hardness attributed to the positive trend of chloro-alkaline indices depicting the ion-exchange phenomenon between Na+ and K+ (alkalies) and Ca2+ and Mg2+ (alkali-earth) elements in the zeolitic zone, 3) Gibbs plot shows the rock–water interaction as the predominant mechanism controlling groundwater chemistry in the zeolitic zone, and 4) the groundwater quality parameters from zeolitic zone are found within the permissible limit of WHO drinking water standards.
Environmental Earth Sciences – Springer Journals
Published: Aug 7, 2017
It’s your single place to instantly
discover and read the research
that matters to you.
Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.
All for just $49/month
Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly
Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.
Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.
Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.
All the latest content is available, no embargo periods.
“Hi guys, I cannot tell you how much I love this resource. Incredible. I really believe you've hit the nail on the head with this site in regards to solving the research-purchase issue.”Daniel C.
“Whoa! It’s like Spotify but for academic articles.”@Phil_Robichaud
“I must say, @deepdyve is a fabulous solution to the independent researcher's problem of #access to #information.”@deepthiw
“My last article couldn't be possible without the platform @deepdyve that makes journal papers cheaper.”@JoseServera