Naphthazarin, a simple model of important antitumor agents in a facile size-tunable synthesis of gold nanoparticles

Naphthazarin, a simple model of important antitumor agents in a facile size-tunable synthesis of... Res Chem Intermed (2015) 41:5985–5993 DOI 10.1007/s11164-014-1715-5 Naphthazarin, a simple model of important antitumor agents in a facile size-tunable synthesis of gold nanoparticles • • Neda Attaran Hossein Eshghi Mohammad Rahimizadeh Mehdi Bakavoli Received: 8 January 2014 / Accepted: 15 May 2014 / Published online: 3 June 2014 Springer Science+Business Media Dordrecht 2014 Abstract 2,3-Dihydro-5,8-dihydroxynaphthalene-1,4-dione (naphthazarin) (2) is used for the first time as a biologically important reagent in the synthesis of gold nanoparticles in water–methanol medium through the chemical reduction of HAuCl at room tem- perature without using any capping agents other than naphthazarin. The ratio of HAuCl and naphthazarin played a vital role in controlling the shape and size of gold nano- particles. Three samples with significant differences in sizes (range of 10–200 nm) have been prepared through increasing the initial naphthazarin/HAuCl molar ratio from 50 to 200. The size, distribution, and formation of gold nanoparticles were confirmed by transmission electron microscopy, Fourier transform infrared spectroscopy, and UV– Visible absorption spectroscopic measurements. Keywords Naphthazarin  2,3-Dihydro-5,8-dihydroxynaphthalene-1,4-dione Gold nanoparticles  Biologically important reagents Introduction Hydroquinone is produced industrially and has a wide variety of uses principally associated with its action as a reducing agent. This application exploits the http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Naphthazarin, a simple model of important antitumor agents in a facile size-tunable synthesis of gold nanoparticles

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Publisher
Springer Netherlands
Copyright
Copyright © 2014 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-014-1715-5
Publisher site
See Article on Publisher Site

Abstract

Res Chem Intermed (2015) 41:5985–5993 DOI 10.1007/s11164-014-1715-5 Naphthazarin, a simple model of important antitumor agents in a facile size-tunable synthesis of gold nanoparticles • • Neda Attaran Hossein Eshghi Mohammad Rahimizadeh Mehdi Bakavoli Received: 8 January 2014 / Accepted: 15 May 2014 / Published online: 3 June 2014 Springer Science+Business Media Dordrecht 2014 Abstract 2,3-Dihydro-5,8-dihydroxynaphthalene-1,4-dione (naphthazarin) (2) is used for the first time as a biologically important reagent in the synthesis of gold nanoparticles in water–methanol medium through the chemical reduction of HAuCl at room tem- perature without using any capping agents other than naphthazarin. The ratio of HAuCl and naphthazarin played a vital role in controlling the shape and size of gold nano- particles. Three samples with significant differences in sizes (range of 10–200 nm) have been prepared through increasing the initial naphthazarin/HAuCl molar ratio from 50 to 200. The size, distribution, and formation of gold nanoparticles were confirmed by transmission electron microscopy, Fourier transform infrared spectroscopy, and UV– Visible absorption spectroscopic measurements. Keywords Naphthazarin  2,3-Dihydro-5,8-dihydroxynaphthalene-1,4-dione Gold nanoparticles  Biologically important reagents Introduction Hydroquinone is produced industrially and has a wide variety of uses principally associated with its action as a reducing agent. This application exploits the

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Jun 3, 2014

References

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