Decomposition kinetics of tertiary cumene hydroperoxides and tert-butyl in ethylbenzene in the presence N,N-diethyldithiocarbamates of 3d metals was studied at moderately low temperatures, 323–383 K. The kinetic parameters of the catalytic decomposition of the hydroperoxides were calculated and a decrease in the activation energy as compared with the thermal decomposition was noted.
Russian Journal of Applied Chemistry – Springer Journals
Published: Jun 17, 2014
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