N-hydroxyphthalimide incorporated onto Cu-BTC metal organic frameworks: An novel catalyst for aerobic oxidation of toluene

N-hydroxyphthalimide incorporated onto Cu-BTC metal organic frameworks: An novel catalyst for... N-hydroxyphthalimide (NHPI) incorporated onto a Cu-based metal–organic framework [NHPI/Cu-BTC (BTC:1,3,5-benzenetricarboxylate)] was prepared and used as a heterogeneous catalyst for aerobic oxidation of toluene under solvent-free conditions. Cu-BTC was synthesized through a hydrothermal and a solvothermal method with modification. The NHPI/Cu-BTC catalysts were synthesized by an impregnation method and characterized by scanning electron microscopy, X-ray diffractometry, Fourier transformed infrared spectroscopy, thermogravimetric analysis, and nitrogen adsorption. Results show NHPI was successfully incorporated onto Cu-BTC metal organic frameworks. The NHPI/Cu-BTC showed high catalytic performance in the aerobic oxidation of toluene. In the presence of 1 mol% NHPI/Cu-BTC and absence of any co-catalyst or co-solvent, the toluene oxidation was conducted at 110 °C for 2 h with 7.6 % conversion and more than 50 % benzaldehyde and benzyl alcohol selectivity. The structure stability of the catalysts after recovery was also studied. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

N-hydroxyphthalimide incorporated onto Cu-BTC metal organic frameworks: An novel catalyst for aerobic oxidation of toluene

Loading next page...
 
/lp/springer_journal/n-hydroxyphthalimide-incorporated-onto-cu-btc-metal-organic-frameworks-hAs56MysJu
Publisher
Springer Netherlands
Copyright
Copyright © 2015 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-015-2384-8
Publisher site
See Article on Publisher Site

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

Monthly Plan

  • Read unlimited articles
  • Personalized recommendations
  • No expiration
  • Print 20 pages per month
  • 20% off on PDF purchases
  • Organize your research
  • Get updates on your journals and topic searches

$49/month

Start Free Trial

14-day Free Trial

Best Deal — 39% off

Annual Plan

  • All the features of the Professional Plan, but for 39% off!
  • Billed annually
  • No expiration
  • For the normal price of 10 articles elsewhere, you get one full year of unlimited access to articles.

$588

$360/year

billed annually
Start Free Trial

14-day Free Trial