Multifunctional Gas Adsorption and Photocatalytic Degradation Based on a Porous Metal-Organic Framework Material

Multifunctional Gas Adsorption and Photocatalytic Degradation Based on a Porous Metal-Organic... The reaction of Cu(NO3)2 · 3H2O with rigid ligand 4'-(1H-tetrazol-5-yl)-[1,1'-biphenyl]-3,5-dicarboxylic acid (H3L) gave a new metal-organic framework of [Cu2(μ3-OH)(L)(H2O)2] n (I) (CIF file CCDC no. 1533273). Complex I has a truncated cuboctahedra that was connected by trigonal Cu3O(N4CR)3 trimers using each tetrazolate (N4CR) moiety and shows a overall 3D nnt net with (6.82)6(83)2(62.84)3 topology. The properties of gas adsorption and the degradation of the methyl violet have been examined. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Multifunctional Gas Adsorption and Photocatalytic Degradation Based on a Porous Metal-Organic Framework Material

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Publisher
Springer Journals
Copyright
Copyright © 2018 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328418030077
Publisher site
See Article on Publisher Site

Abstract

The reaction of Cu(NO3)2 · 3H2O with rigid ligand 4'-(1H-tetrazol-5-yl)-[1,1'-biphenyl]-3,5-dicarboxylic acid (H3L) gave a new metal-organic framework of [Cu2(μ3-OH)(L)(H2O)2] n (I) (CIF file CCDC no. 1533273). Complex I has a truncated cuboctahedra that was connected by trigonal Cu3O(N4CR)3 trimers using each tetrazolate (N4CR) moiety and shows a overall 3D nnt net with (6.82)6(83)2(62.84)3 topology. The properties of gas adsorption and the degradation of the methyl violet have been examined.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Mar 13, 2018

References

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