Morphology and magnetic properties of synthesized lipid packaged iron(II) complex

Morphology and magnetic properties of synthesized lipid packaged iron(II) complex Lipid packaged iron(II) complex of [Fe(C C C -trz) ](C -Glu) (1) [C C C -trz = 4′,5‴-decyl-1‴-(heptadecyloxy)- 5 10 12 3 12 2 5 10 12 1,2,4-triazole, C -Glu = 4-(1,3-bis-dodecyloxycarbonyl-propylcarbamoyl)-benzenesulfonic acid] have been successfully synthesized and characterized using TEM, DSC, PXRD and magnetic susceptibility. It was observed that lipid packaged compound displayed liquid crystalline phase at room temperature. Furthermore, lipid packaged compound exhibited spin crossover phenomena accompanying the phase transition from liquid crystalline to liquid crystalline. Keywords Iron(II) · Lipid amphiphile · Spin-crossover · Liquid crystalline Introduction chain showed liquid crystalline phase at 233 K and abrupt spin crossover behavior at T = 250 K [12]. 1/2 Self-assembly of metal complexes have attracted much atten- Hereby, in the present study, we mainly focused lipid tion as can be applied to the development of multi-functional amphiphiles as a method for self-assembly of metal com- materials [1, 2]. Among various types of functional metal plexes to be used as spin crossover metal complexes. The complexes, spin crossover complexes have been well stud- lipid amphiphiles make it possible to aggregate [13] and ied for the development of information storage, molecular self-assemble functional coordination system. Moreover, the switching and display devices. It is also well known http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Inclusion Phenomena and Macrocyclic Chemistry Springer Journals

Morphology and magnetic properties of synthesized lipid packaged iron(II) complex

Loading next page...
 
/lp/springer_journal/morphology-and-magnetic-properties-of-synthesized-lipid-packaged-iron-aQnursPNAV
Publisher
Springer Journals
Copyright
Copyright © 2018 by Springer Science+Business Media B.V., part of Springer Nature
Subject
Chemistry; Organic Chemistry; Food Science; Crystallography and Scattering Methods
ISSN
1388-3127
eISSN
1573-1111
D.O.I.
10.1007/s10847-018-0815-z
Publisher site
See Article on Publisher Site

Abstract

Lipid packaged iron(II) complex of [Fe(C C C -trz) ](C -Glu) (1) [C C C -trz = 4′,5‴-decyl-1‴-(heptadecyloxy)- 5 10 12 3 12 2 5 10 12 1,2,4-triazole, C -Glu = 4-(1,3-bis-dodecyloxycarbonyl-propylcarbamoyl)-benzenesulfonic acid] have been successfully synthesized and characterized using TEM, DSC, PXRD and magnetic susceptibility. It was observed that lipid packaged compound displayed liquid crystalline phase at room temperature. Furthermore, lipid packaged compound exhibited spin crossover phenomena accompanying the phase transition from liquid crystalline to liquid crystalline. Keywords Iron(II) · Lipid amphiphile · Spin-crossover · Liquid crystalline Introduction chain showed liquid crystalline phase at 233 K and abrupt spin crossover behavior at T = 250 K [12]. 1/2 Self-assembly of metal complexes have attracted much atten- Hereby, in the present study, we mainly focused lipid tion as can be applied to the development of multi-functional amphiphiles as a method for self-assembly of metal com- materials [1, 2]. Among various types of functional metal plexes to be used as spin crossover metal complexes. The complexes, spin crossover complexes have been well stud- lipid amphiphiles make it possible to aggregate [13] and ied for the development of information storage, molecular self-assemble functional coordination system. Moreover, the switching and display devices. It is also well known

Journal

Journal of Inclusion Phenomena and Macrocyclic ChemistrySpringer Journals

Published: May 28, 2018

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Search

Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly

Organize

Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.

Access

Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve

Freelancer

DeepDyve

Pro

Price

FREE

$49/month
$360/year

Save searches from
Google Scholar,
PubMed

Create lists to
organize your research

Export lists, citations

Read DeepDyve articles

Abstract access only

Unlimited access to over
18 million full-text articles

Print

20 pages / month

PDF Discount

20% off