Montmorillonite-supported KF/CaO: a new solid base catalyst for biodiesel production

Montmorillonite-supported KF/CaO: a new solid base catalyst for biodiesel production Biodiesel is an alternative to petroleum-derived diesel fuel; development of a high-efficiency base catalyst to be used in heterogeneous biodiesel production is still a challenge. In this paper, a novel solid base catalyst, KF- and CaO-supported montmorillonite (KCa/MMT) was successfully synthesized by a facile impregnation method, and used for producing biodiesel in transesterification of commercial soybean oil with methanol. The catalysts were characterized by X-ray diffraction, carbon dioxide temperature-programmed desorption and scanning electron microscopy. Effects of the parameters, such as the loading amount of KF, the amount of KCa/MMT, and the methanol to oil molar ratios, on the yield of biodiesel were investigated. A maximum biodiesel yield of 98 % was obtained under the optimal reaction conditions. The separated catalyst can be directly used in the next round of reactions and gave a satisfactory yield. Furthermore, analysis of the catalyst's tolerance to oil-containing water or free fatty acids, and a kinetic study were also carried out. Koros–Nowak tests were designed and conducted, and it was proven that the heat and mass transfer were not limited by the reaction rate. Research on Chemical Intermediates Springer Journals

Montmorillonite-supported KF/CaO: a new solid base catalyst for biodiesel production

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Springer Netherlands
Copyright © 2015 by Springer Science+Business Media Dordrecht
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
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