Molecular Transport of Xylene Through Palm Pressed Fibre Filled Low Density Polyethylene: Role of Fibre Content, Alkali Treatment and Particle Size

Molecular Transport of Xylene Through Palm Pressed Fibre Filled Low Density Polyethylene: Role of... We report in this paper the transport of an aromatic solvent, xylene through palm pressed fibre filled low density polyethylene composites studied at three different temperatures (40, 60, and 80 °C) by conventional weight-gain method. The diffusion parameters were investigated with special reference to the effect of fibre content, temperature and particle size. The effect of alkali treatment on solvent uptake was also analyzed. The transport coefficients of diffusion, permeation and sorption were determined to evaluate the influence of interface bonding on transport properties. The van’t Hoff relationship was used to determine the thermodynamic parameters and was found that the estimated free energies of sorption were all positive, indicating non-spontaneity of the solubility of PPF/LDPE composites. The first order kinetic rate constant and swelling parameters were also evaluated. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Polymers and the Environment Springer Journals

Molecular Transport of Xylene Through Palm Pressed Fibre Filled Low Density Polyethylene: Role of Fibre Content, Alkali Treatment and Particle Size

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Publisher
Springer US
Copyright
Copyright © 2016 by Springer Science+Business Media New York
Subject
Chemistry; Polymer Sciences; Environmental Chemistry; Materials Science, general; Environmental Engineering/Biotechnology; Industrial Chemistry/Chemical Engineering
ISSN
1566-2543
eISSN
1572-8900
D.O.I.
10.1007/s10924-016-0835-y
Publisher site
See Article on Publisher Site

Abstract

We report in this paper the transport of an aromatic solvent, xylene through palm pressed fibre filled low density polyethylene composites studied at three different temperatures (40, 60, and 80 °C) by conventional weight-gain method. The diffusion parameters were investigated with special reference to the effect of fibre content, temperature and particle size. The effect of alkali treatment on solvent uptake was also analyzed. The transport coefficients of diffusion, permeation and sorption were determined to evaluate the influence of interface bonding on transport properties. The van’t Hoff relationship was used to determine the thermodynamic parameters and was found that the estimated free energies of sorption were all positive, indicating non-spontaneity of the solubility of PPF/LDPE composites. The first order kinetic rate constant and swelling parameters were also evaluated.

Journal

Journal of Polymers and the EnvironmentSpringer Journals

Published: Sep 17, 2016

References

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